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Palm oil-based biodiesel synthesis by radiation-induced kenaf catalyst packed in a continuous flow system
https://repo.qst.go.jp/records/76685
https://repo.qst.go.jp/records/766853848389f-0cff-4e67-bc0d-8f7d02c3c829
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-09-04 | |||||
| タイトル | ||||||
| タイトル | Palm oil-based biodiesel synthesis by radiation-induced kenaf catalyst packed in a continuous flow system | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
Haryani Zabaruddin, Nur
× Haryani Zabaruddin, Nur× Hasimah Mohamed, Nor× Chuah Abdullah, Luqman× Tamada, Masao× Ueki, Yuuji× Seko, Noriaki× Shean Yaw Choong, Thomas× Tamada, Masao× Ueki, Yuuji× Seko, Noriaki |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | An efficient bio-based heterogeneous catalyst for biodiesel production was successfully fabricated by radiation-induced graft polymerization of 4-vinylbenzylchloride (VBC) followed by quaternary amination of trimethylamine (TMA) and ion-exchange with aqueous sodium hydroxide onto kenaf bast fiber using electron beam irradiation at a dose of 150 kGy. The produced catalyst was characterized by FESEM–EDX, CHNS, ATR-FTIR, TGA and XRD analyses. In this study, the continuous catalytic transesterification of triolein/ethanol in a bench-scale packed bed reactor (PBR) was designed and tested. The reaction process was focused at room temperature, different residence times from 1 min to 4 min and a molar ratio of triolein/ethanol (1:50). Besides, study on the transesterification of palm oil with ethanol under optimized conditions for maximum conversion of triolein to ethyl oleate (residence time of 3 min, LHSV = 8 h^−1, short chain 150kGy catalyst) with temperature fixed at room temperature (˜25 °C) has been carried out. The extracted ethyl oleate was analyzed by HPLC and ATR-FTIR. The results found that the continuous flow system has a great potential for producing ethyl ester to be used as biodiesel and it is possible to generate 100% biodiesel with high purity from palm oil using radiation-induced kenaf catalyst. | |||||
| 書誌情報 |
Industrial Crops and Products 巻 136, p. 102-109, 発行日 2019-05 |
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| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0926-6690 | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.indcrop.2019.04.069 | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://www.sciencedirect.com/science/article/abs/pii/S092666901930319X | |||||
