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Formation of novel transition metal hydride complexes with ninefold hydrogen coordination
https://repo.qst.go.jp/records/48061
https://repo.qst.go.jp/records/480618623ab07-8a8c-4bf6-9560-15c7e315d5d9
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-06-22 | |||||
| タイトル | ||||||
| タイトル | Formation of novel transition metal hydride complexes with ninefold hydrogen coordination | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
Takagi, Shigeyuki
× Takagi, Shigeyuki× Iijima, yuki× Sato, Toyoto× 齋藤, 寛之× Ikeda, Kazutaka× Otomo, Toshiya× Miwa, Kazutoshi× Ikeshoji, Tamio× Orimo, Shin-ichi× 齋藤 寛之 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Ninefold coordination of hydrogen is very rare, and has been observed in two different hydride complexes comprising rhenium and technetium. Herein, based on a theoretical/experimental approach, we present evidence for the formation of ninefold H- coordination hydride complexes of molybdenum ([MoH9]3-), tungsten ([WH9]3-), niobium ([NbH9]4-) and tantalum ([TaH9]4-) in novel complex transition-metal hydrides, Li5MoH11, Li5WH11, Li6NbH11 and Li6TaH11, respectively. | |||||
| 書誌情報 |
Scientific Reports 巻 7, p. 44253, 発行日 2017-03 |
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| 出版者 | ||||||
| 出版者 | Macmillan Publishers Limited, part of Springer Nature | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1038/srep44253 | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.nature.com/articles/srep44253 | |||||
| 関連名称 | http://www.nature.com/articles/srep44253 | |||||
