@article{oai:repo.qst.go.jp:00048061, author = {Takagi, Shigeyuki and Iijima, yuki and Sato, Toyoto and 齋藤, 寛之 and Ikeda, Kazutaka and Otomo, Toshiya and Miwa, Kazutoshi and Ikeshoji, Tamio and Orimo, Shin-ichi and 齋藤 寛之}, journal = {Scientific Reports}, month = {Mar}, note = {Ninefold coordination of hydrogen is very rare, and has been observed in two different hydride complexes comprising rhenium and technetium. Herein, based on a theoretical/experimental approach, we present evidence for the formation of ninefold H- coordination hydride complexes of molybdenum ([MoH9]3-), tungsten ([WH9]3-), niobium ([NbH9]4-) and tantalum ([TaH9]4-) in novel complex transition-metal hydrides, Li5MoH11, Li5WH11, Li6NbH11 and Li6TaH11, respectively.}, title = {Formation of novel transition metal hydride complexes with ninefold hydrogen coordination}, volume = {7}, year = {2017} }