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Chelating Fabrics Prepared by an Organic Solvent-Free Process for Boron Removal from Water
https://repo.qst.go.jp/records/85329
https://repo.qst.go.jp/records/85329f0716237-9ff4-4747-84f6-1cfcddc306bc
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-10-07 | |||||
タイトル | ||||||
タイトル | Chelating Fabrics Prepared by an Organic Solvent-Free Process for Boron Removal from Water | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Hiroyuki, Hoshina
× Hiroyuki, Hoshina× Jinhua, Chen× Haruyo, Amada× Noriaki, Seko× Hiroyuki, Hoshina× Jinhua, Chen× Haruyo, Amada× Noriaki, Seko |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A chelating fabric was prepared by graft polymerization of glycidyl methacrylate (GMA) onto a nonwoven fabric, followed by attachment reaction of N-methyl-D-glucamine (NMDG) using an organic solvent-free process. The graft polymerization was performed by immersing the gamma-ray pre-irradiated fabric into the GMA emulsion, while the attachment reaction was carried out by immersing the grafted fabric in the NMDG aqueous solution. The chelating capacity of the chelating fabric prepared by reaction in the NMDG aqueous solution without any additives reached 1.74 mmol/g, which further increased to above 2.0 mmol/g when surfactant and acid catalyst were added in the solution. The boron chelation of the chelating fabric was evaluated in a batch mode. Fourier transform infrared spectrophotometer (FTIR) was used to characterize the fabrics. The chelating fabric can quickly chelate boron from water to form a boron ester, and a high boron chelating ability close to 18.3 mg/g was achieved in the concentrated boron solution. The chelated boron can be eluted completely by HCl solution. The regeneration and stability of the chelating fabric were tested by 10 cycles of the chelation-elution operations. Considering the organic solvent-free preparation process and the high boron chelating performance, the chelating fabric is promising for the boron removal from water. | |||||
書誌情報 |
Polymers 巻 13, 号 7, p. 1163, 発行日 2021-04 |
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出版者 | ||||||
出版者 | MDPI | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2073-4360 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.3390/polym13071163 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.mdpi.com/2073-4360/13/7/1163 |