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  1. 原著論文

Chelating Fabrics Prepared by an Organic Solvent-Free Process for Boron Removal from Water

https://repo.qst.go.jp/records/85329
https://repo.qst.go.jp/records/85329
f0716237-9ff4-4747-84f6-1cfcddc306bc
Item type 学術雑誌論文 / Journal Article(1)
公開日 2021-10-07
タイトル
タイトル Chelating Fabrics Prepared by an Organic Solvent-Free Process for Boron Removal from Water
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Hiroyuki, Hoshina

× Hiroyuki, Hoshina

WEKO 1028472

Hiroyuki, Hoshina

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Jinhua, Chen

× Jinhua, Chen

WEKO 1028473

Jinhua, Chen

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Haruyo, Amada

× Haruyo, Amada

WEKO 1028474

Haruyo, Amada

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Noriaki, Seko

× Noriaki, Seko

WEKO 1028475

Noriaki, Seko

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Hiroyuki, Hoshina

× Hiroyuki, Hoshina

WEKO 1028476

en Hiroyuki, Hoshina

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Jinhua, Chen

× Jinhua, Chen

WEKO 1028477

en Jinhua, Chen

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Haruyo, Amada

× Haruyo, Amada

WEKO 1028478

en Haruyo, Amada

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Noriaki, Seko

× Noriaki, Seko

WEKO 1028479

en Noriaki, Seko

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抄録
内容記述タイプ Abstract
内容記述 A chelating fabric was prepared by graft polymerization of glycidyl methacrylate (GMA) onto a nonwoven fabric, followed by attachment reaction of N-methyl-D-glucamine (NMDG) using an organic solvent-free process. The graft polymerization was performed by immersing the gamma-ray pre-irradiated fabric into the GMA emulsion, while the attachment reaction was carried out by immersing the grafted fabric in the NMDG aqueous solution. The chelating capacity of the chelating fabric prepared by reaction in the NMDG aqueous solution without any additives reached 1.74 mmol/g, which further increased to above 2.0 mmol/g when surfactant and acid catalyst were added in the solution. The boron chelation of the chelating fabric was evaluated in a batch mode. Fourier transform infrared spectrophotometer (FTIR) was used to characterize the fabrics. The chelating fabric can quickly chelate boron from water to form a boron ester, and a high boron chelating ability close to 18.3 mg/g was achieved in the concentrated boron solution. The chelated boron can be eluted completely by HCl solution. The regeneration and stability of the chelating fabric were tested by 10 cycles of the chelation-elution operations. Considering the organic solvent-free preparation process and the high boron chelating performance, the chelating fabric is promising for the boron removal from water.
書誌情報 Polymers

巻 13, 号 7, p. 1163, 発行日 2021-04
出版者
出版者 MDPI
ISSN
収録物識別子タイプ ISSN
収録物識別子 2073-4360
DOI
識別子タイプ DOI
関連識別子 10.3390/polym13071163
関連サイト
識別子タイプ URI
関連識別子 https://www.mdpi.com/2073-4360/13/7/1163
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