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  1. 原著論文

Phase decomposition of oxide film of flow accelerated corroded F82H steel under high-temperature iron irradiation

https://repo.qst.go.jp/records/85090
https://repo.qst.go.jp/records/85090
6bdafc71-1499-4b30-979c-df0864133377
Item type 学術雑誌論文 / Journal Article(1)
公開日 2022-03-04
タイトル
タイトル Phase decomposition of oxide film of flow accelerated corroded F82H steel under high-temperature iron irradiation
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Sho, Kano

× Sho, Kano

WEKO 1046278

Sho, Kano

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Yang, Huilong

× Yang, Huilong

WEKO 1046279

Yang, Huilong

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McGrady, John

× McGrady, John

WEKO 1046280

McGrady, John

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Motoki, Nakajima

× Motoki, Nakajima

WEKO 1046281

Motoki, Nakajima

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Masami, Ando

× Masami, Ando

WEKO 1046282

Masami, Ando

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Takashi, Nozawa

× Takashi, Nozawa

WEKO 1046283

Takashi, Nozawa

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Hiroaki, Abe

× Hiroaki, Abe

WEKO 1046284

Hiroaki, Abe

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Motoki, Nakajima

× Motoki, Nakajima

WEKO 1046285

en Motoki, Nakajima

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Masami, Ando

× Masami, Ando

WEKO 1046286

en Masami, Ando

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Takashi, Nozawa

× Takashi, Nozawa

WEKO 1046287

en Takashi, Nozawa

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抄録
内容記述タイプ Abstract
内容記述 The purpose of the present study is to clarify the phase stability of the corroded layer in reduced activation ferritic/martensitic steels under irradiation. The oxide film of F82H steel was subjected to ion irradiation using 2.8 MeV-Fe2+ at 573 K. For post-irradiation experiments, grazing incident X-ray diffraction (GIXRD) and Raman analysis was conducted to clarify the features of the oxide layer with variation of the irradiation dose. The dominant phase of the oxide film was identified as FeCr2O4, which co-existed with up to ~30% of the residual matrix phase. The fraction of the residual matrix decreased as the irradiation dose increased, the phase transformation from FeCr2O4 to Fe3O4 was confirmed. The hypothesis for the phase transformation of FeCr2O4 to Fe3O4 under irradiation was proposed based on the experimental results. Specifically, FeCr2O4 phase is unstable under irradiation, and tends to become stable after absorbing Fe atoms from the residual matrix in the corrosion layer. As a result, the Fe concentration in the oxide layer increased under irradiation, the phase transformation of FeCr2O4 to Fe3O4 is presumed under irradiation. However, concerns of the mechanism about the instability of FeCr2O4 under irradiation, and better stability of Fe3O4 phase relative to FeCr2O4 phase have to be further considered to achieve a better understanding.
書誌情報 Journal of Nuclear Materials

巻 563, p. 153639, 発行日 2022-03
ISSN
収録物識別子タイプ ISSN
収録物識別子 0022-3115
DOI
識別子タイプ DOI
関連識別子 10.1016/j.jnucmat.2022.153639
関連サイト
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.jnucmat.2022.153639
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