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A Novel Method for the Measurement of 90Sr Using Thermal Ionization Mass Spectrometer

https://repo.qst.go.jp/records/85055
https://repo.qst.go.jp/records/85055
e33e7cfb-0967-4ee2-a983-abc91ed0e754
Item type 会議発表用資料 / Presentation(1)
公開日 2022-01-13
タイトル
タイトル A Novel Method for the Measurement of 90Sr Using Thermal Ionization Mass Spectrometer
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_c94f
資源タイプ conference object
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Sahoo, Sarata

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WEKO 1025712

Sahoo, Sarata

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Kavasi, Norbert

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WEKO 1025713

Kavasi, Norbert

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Tatsuo, Aono

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WEKO 1025714

Tatsuo, Aono

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Sahoo, Sarata

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WEKO 1025715

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Kavasi, Norbert

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WEKO 1025716

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Tatsuo, Aono

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WEKO 1025717

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抄録
内容記述タイプ Abstract
内容記述 There is a great demand for rapid measurement of Sr-90 in environmental samples after the Fukushima Dai-ichi nuclear power station (FDNPS) accident. 90Sr (t1/2 = 28.8 y) is one of the most common and hazardous fission products released by a nuclear reactor accident. Measurement of 90Sr using radiometric methods is a time consuming process since it involves a complex sample preparation and analytical separation required to produce reliable data.
Thermal ionization mass spectrometry (TIMS) is the technique of choice because of its inherent high precision and accurate measurement of isotopic ratio. Typical abundance sensitivity for strontium isotope ratio measurement with conventional TIMS is about 10-7. The perfect chemical separation of radiocesium from Sr-90 is a cardinal point to gain accurate Sr-90 result as the radiocesium also undergoes beta decay emitting gamma-rays. A new 90Sr analysis method was developed using the Isotopx Ltd., Phoenix X62 TIMS. The abundance sensitivity for the 90Sr/88Sr ratio was 2.1×10 10 and this could ensure detection limit of 100 Bq·kg 1 (19 fg·g 1) 90Sr in Fukushima soil samples. The method has been validated using two certified reference materials e. g. wild berry (IRMM-426) and freshwater lake sediment (NIST-4354). This mass spectrometry method is faster than conventional radiometric techniques.
会議概要(会議名, 開催地, 会期, 主催者等)
内容記述タイプ Other
内容記述 福島大学環境放射能研究所第8回成果報告会
発表年月日
日付 2022-03-01
日付タイプ Issued
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Ver.1 2023-05-15 17:04:29.170810
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