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Epitaxial-Strain-Induced Spontaneous Magnetization in Polar Mn2Mo3O8
https://repo.qst.go.jp/records/84920
https://repo.qst.go.jp/records/849205d0f7685-cc7c-4da4-a9b0-f495e0c4ee71
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-12-28 | |||||
タイトル | ||||||
タイトル | Epitaxial-Strain-Induced Spontaneous Magnetization in Polar Mn2Mo3O8 | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Mo , Shishin
× Mo , Shishin× Chikamatsu, Akira× Kitamura, Miho× Koji, Horiba× Kumigashira, Hiroshi× Hasegawa, Tetsuya× Koji, Horiba |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Mn2Mo3O8 simultaneously exhibits ferroelectric polarization and unique magnetic properties, such as strong magnetoelectric coupling and magnetic-field-induced collinear-to-noncollinear spin structure transitions. However, practical applications of multiferroic Mn2Mo3O8 are hindered by low spontaneous magnetization (0.01 μB/f.u. at 2 K) owing to the collinear spin order. Herein, we report the emergence of large spontaneous magnetization of 0.35 μB/f.u. by applying 0.5% tensile strain to c-axis-oriented Mn2Mo3O8 epitaxial films. The Mn and Mo valence states were divalent and tetravalent, respectively. The enhanced spontaneous magnetization was directed in the in-plane direction, in contrast to that in the case of the bulk. These results suggest that the film has a noncollinear spin structure with tilted Mn2+ magnetic moments from the c-axis probably due to the tensile strain. We also performed first-principles calculations and demonstrated that the direction of the Mn2+ magnetic moment is sensitive to tensile strain. | |||||
書誌情報 |
Chemistry of Materials 巻 33, 号 19, p. 7713-7718, 発行日 2021-12 |
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出版者 | ||||||
出版者 | ACS | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0897-4756 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/acs.chemmater.1c01877 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/10.1021/acs.chemmater.1c01877 |