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Electronic and crystal structures of LnFeAsO1−xHx (Ln = La, Sm) studied by x-ray absorption spectroscopy, x-ray emission spectroscopy, and x- ray diffraction: II pressure dependence
https://repo.qst.go.jp/records/83021
https://repo.qst.go.jp/records/83021f8bd5365-7dd3-4471-aee0-a1720a5c28af
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2021-06-23 | |||||
| タイトル | ||||||
| タイトル | Electronic and crystal structures of LnFeAsO1−xHx (Ln = La, Sm) studied by x-ray absorption spectroscopy, x-ray emission spectroscopy, and x- ray diffraction: II pressure dependence | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
Yamamoto, Yoshiya
× Yamamoto, Yoshiya× Yamaoka, Hitoshi× Yoshida, Masahiro× Jun-ichi, Yamaura× Ishii, Kenji× Onari, Seiichiro× Uozumi, Takayuki× Hariki, Atsushi× Kawai, Takuma× Taguchi, Munetaka× Kobayashi, Kensuke× Jung-Fu, Lin× Hiraoka, Nozomu× Ishii, Hirofumi× Ku-DIng, Tsuei× Okanishi, Hiroshi× Iimura, Soshi× Matsuishi, Satoru× Hosono, Hideo× Jun'ichiro, Mizuki× Kenji, Ishii× Junichiro, Mizuki |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | We examine electronic and crystal structures of iron-based superconductors LnFeAsO1−xHx (Ln = La, Sm) under pressure by means of x-ray absorption spectroscopy (XAS), x-ray emission spectroscopy (XES), and x-ray diffraction. In LaFeAsO the pre-edge peak on high-resolution XAS at the Fe-K absorption edge gains in intensity on the application of pressure up to 5.7 GPa and it saturates in the higher pressure region. We found integrated-absolute difference values on XES for Ln = La, corresponding to a spin state, decline on the application of pressure, and then it is minimized when the Tc approaches the maximum at around 5 GPa. In contrast, such the optimum value was not detected for Ln = Sm. We reveal that the superconductivity is closely related to the lower spin state for Ln = La unlike Sm case. We observed that As height from the Fe basal plane and As-Fe-As angle on the FeAs4 tetrahedron for Ln = La deviate from the optimum values of the regular tetrahedron in superconducting (SC) phase, which has been widely accepted structural guide to SC thus far. In contrast, the structural parameters were held near the optimum values up to ∼15 GPa for Ln = Sm. | |||||
| 書誌情報 |
Journal of Physics: Condensed Matter 巻 33, 号 25, p. 255603-1-255603-10, 発行日 2021-06 |
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| 出版者 | ||||||
| 出版者 | IOP publishing | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0953-8984 | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1088/1361-648X/abfaf4 | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://iopscience.iop.org/article/10.1088/1361-648X/abfaf4 | |||||
