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Development of mass spectrometric method for simultaneous
https://repo.qst.go.jp/records/80456
https://repo.qst.go.jp/records/80456fd66d03a-5679-46b0-aaaf-a2e1d5853a67
Item type | 会議発表用資料 / Presentation(1) | |||||
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公開日 | 2020-09-10 | |||||
タイトル | ||||||
タイトル | Development of mass spectrometric method for simultaneous | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_c94f | |||||
資源タイプ | conference object | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Zheng, Jian
× Zheng, Jian× Wang, Hai× Shikamori, Yasuyuki× Ni, Youyi× Aono, Tatsuo× Zheng, Jian× Aono, Tatsuo |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | So far, there is no established mass spectrometric method for simultaneous determination of these hard-to-measure 238Pu, 239Pu, 240Pu and 241Pu in environmental mediums. In this study, we developed an advanced mass spectrometry method for simultaneous analysis of important Pu isotopes (238,239,240,241Pu) using triple quadrupole ICP-MS/MS by employing the ion-molecule reaction separate 238U and 238Pu, which was previously difficult to be measured. By introducing a desolvation sample introduction system, we succeeded in increasing 10 times the sensitivity of Pu isotopes and suppressing the production of uranium hydride, we achieved the detection limit of fg level in on-mass mode. We have developed a new low-temperature fusion method for environmental and nuclear decommissioning samples. By combining these new sample preparation techniques with the developed ICP-MS/MS detection, rapid Pu isotope mass spectrometry methods for environmental samples and decommissioning related waste samples were established. | |||||
会議概要(会議名, 開催地, 会期, 主催者等) | ||||||
内容記述タイプ | Other | |||||
内容記述 | 日本放射化学会第64回討論会(2020) | |||||
発表年月日 | ||||||
日付 | 2020-09-09 | |||||
日付タイプ | Issued |