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Precise Measurement of Tellurium Isotope Ratios in Terrestrial Standards Using a Multiple Collector Inductively Coupled Plasma Mass Spectrometry
https://repo.qst.go.jp/records/79923
https://repo.qst.go.jp/records/799239fbc9008-9418-4557-bd57-a8201db2ee72
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-04-28 | |||||
タイトル | ||||||
タイトル | Precise Measurement of Tellurium Isotope Ratios in Terrestrial Standards Using a Multiple Collector Inductively Coupled Plasma Mass Spectrometry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Murugan, Rajamanickam
× Murugan, Rajamanickam× Tatsuo, Aono× Sahoo, Sarata× Murugan, Rajamanickam× Tatsuo, Aono× Sahoo, Sarata |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Precise tellurium (Te) isotope ratio measurement using mass spectrometry is a challenging task for many decades. In this paper, Te isotope ratio measurements using multi-collector inductively coupled plasma mass spectrometry (MC–ICP–MS) in terrestrial Te standards have been reported. Newly developed Faraday cup with 1e12 ohm resistor is used to measure low abundance 120Te, whereas the 1e11 ohm resistor is used to measure other Te isotopes. The relative standard deviation obtained for Te isotope ratio measurement by Faraday cups of 120Te/128Te [0.002907(05)], 122Te/128Te [0.079646(10)], 123Te/128Te [0.027850(07)], 125Te/128Te [0.221988(09)], 126Te/128Te [0.592202(20)], and 130Te/128Te [1.076277(30)] were 0.140%, 0.014%, 0.026%, 0.005%, 0.004%, and 0.004%, respectively. The measured isotope ratio results are compared with previous results obtained by thermal ionization mass spectrometry (TIMS), negative thermal ionization mass spectrometry (N–TIMS), and MC–ICP–MS, showing an improvement in the precision about one order of magnitude for 120Te/128Te ratio. The present study shows better precision for Te isotope ratios compared to earlier studies. |
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書誌情報 |
Molecules 巻 25, 号 8, p. 1959, 発行日 2020-04 |
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出版者 | ||||||
出版者 | MDPI publisher | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1420-3049 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.3390/molecules25081956 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.mdpi.com/ |