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Thermally stable graft-type polymer electrolyte membranes consisting based on poly (ether ether ketone) and crosslinked graft-polymers for fuel cell applications
https://repo.qst.go.jp/records/78214
https://repo.qst.go.jp/records/78214ab8b247c-c39a-4063-9af7-3ef96c6e0d05
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-12-23 | |||||
| タイトル | ||||||
| タイトル | Thermally stable graft-type polymer electrolyte membranes consisting based on poly (ether ether ketone) and crosslinked graft-polymers for fuel cell applications | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
Hasegawa, Shin
× Hasegawa, Shin× Hiroki, Akihiro× Maekawa, Yasunari× Ohta, Yuko× Iimura, Nobuaki× Fukaya, Atsuko× Shin, Hasegawa× Akihiro, Hiroki× Yasunari, Maekawa |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The effect of crosslinking on the thermal stability of poly (styrenesulfonic acid)-grafted poly (ether ether ketone) polymer electrolyte membranes (PEEK-PEMs) was investigated in water at 120 °C. The radiation-induced graft polymerization of an ethyl 4-styrenesulfonate (ETSS) monomer onto PEEK substrates, with divinylbenzene (DVB) (0.05, 0.1, 0.2, and 0.5wt.%) as a crosslinker, followed by hydrolysis, generated crosslinker-containing PEEK-PEMs (PEEK-×0.05, -×0.1, -×0.2, and -×0.5), because the crosslinker (up to 0.5wt.%) did not cause any destructive effect on the on grafting and hydrolysis rates. As a result, grafting degrees of 100–114% and ion exchange capacities (IECs) of 2.2–2.7 mmol/g, respectively, were achieved. Increasing the DVB amounts (from 0 to 0.5 wt.%), the conductivity, and water uptakes decreased; the PEEK-×0.5 showed a conductivity of 0.10 S/cm and water uptake of 43%. This confirms the successful incorporation of crosslinking structures on the graft-polymers. The hydrothermal test involved the immersion of PEMs in water at 120 °C for 500 hours. The no-crosslinked PEEK-PEMs with the same IEC (2.7 mmol/g) experienced a decreases in the weight and IEC to 84 and 68% levels from the initial values, respectively, while those of crosslinked PEEK-×0.05 almost maintained their initial values (100 and 96%, respectively). These results indicated that very small amounts of crosslinkers can decreases the conductivity and the water absorption tendency while increasing the hydrothermal stability at higher temperatures. | |||||
| 書誌情報 |
Radiation Physics and Chemistry 巻 171, p. 108647, 発行日 2019-12 |
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| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0969-806X | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.radphyschem.2019.108647 | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://www.sciencedirect.com/science/article/pii/S0969806X19312216 | |||||
