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Long-term Oxidative Degradation of Electron Beam Irradiated High Density Polyethylene Studied by Positron Annihilation Technique

https://repo.qst.go.jp/records/72873
https://repo.qst.go.jp/records/72873
574d60ee-e351-466e-9be1-4bd643dbbca4
Item type 会議発表用資料 / Presentation(1)
公開日 2018-07-23
タイトル
タイトル Long-term Oxidative Degradation of Electron Beam Irradiated High Density Polyethylene Studied by Positron Annihilation Technique
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_c94f
資源タイプ conference object
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 T.Oka

× T.Oka

WEKO 718045

T.Oka

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N.Nagasawa

× N.Nagasawa

WEKO 718046

N.Nagasawa

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Y.Kino

× Y.Kino

WEKO 718047

Y.Kino

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T.Sekine

× T.Sekine

WEKO 718048

T.Sekine

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長澤 尚胤

× 長澤 尚胤

WEKO 718049

en 長澤 尚胤

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内容記述タイプ Abstract
内容記述 Structural change and degradation of electron-beam irradiated high density polyethylene was investigated by a conventional positron annihilation lifetime spectroscopy (PALS) using 22Na positron source, gel fraction measurement, and micro-FT-IR spectroscopy immediately after the irradiation and after 3 years storage in air. The pick-off annihilation intensity of ortho-positronium (o-Ps) became small by the irradiation and after the storage maybe due to the trapping of positron by radicals/carbonyl groups. On the other hand, o-Ps lifetime did not change by the irradiation and the storage. It suggests that size of nanometer-sized free-volume is not affected by the structural change such as oxidation and cross-linking.
会議概要(会議名, 開催地, 会期, 主催者等)
内容記述タイプ Other
内容記述 The 13th meeting of the “Ionizing Radiation and Polymers” symposium (IRaP2018)
発表年月日
日付 2018-08-27
日付タイプ Issued
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