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Novel method for determination of 90Sr using Thermal Ionization Mass Spectrometry

https://repo.qst.go.jp/records/65947
https://repo.qst.go.jp/records/65947
418545e8-d478-4b48-8c42-8b352167400a
Item type 会議発表用資料 / Presentation(1)
公開日 2016-09-02
タイトル
タイトル Novel method for determination of 90Sr using Thermal Ionization Mass Spectrometry
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_c94f
資源タイプ conference object
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Kumar, Sahoo Sarata

× Kumar, Sahoo Sarata

WEKO 649581

Kumar, Sahoo Sarata

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Kavasi, Norbert

× Kavasi, Norbert

WEKO 649582

Kavasi, Norbert

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Aono, Tatsuo

× Aono, Tatsuo

WEKO 649583

Aono, Tatsuo

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Palacz, Zenon

× Palacz, Zenon

WEKO 649584

Palacz, Zenon

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サフー サラタ クマール

× サフー サラタ クマール

WEKO 649585

en サフー サラタ クマール

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Kavasi Norbert

× Kavasi Norbert

WEKO 649586

en Kavasi Norbert

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青野 辰雄

× 青野 辰雄

WEKO 649587

en 青野 辰雄

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抄録
内容記述タイプ Abstract
内容記述 Measurement of radioactive strontium, one of the most common and hazardous fission product after e.g. a reactor accident are carried out to determine the primary strontium isotope of interest, the long lived 90Sr (t1/2 =28.8 y). 90Sr has a long biological half-life (~18y) in the human body. Due to its chemical similarity to calcium, it accumulates in bones and irradiates the bone marrow, causing its high radio-toxicity. Therefore, to assess 90Sr is important in case of a nuclear disaster. The fission yield of stable 88Sr (˜3.5×10-2) isotope in thermal neutron fission is comparable with the radioactive 90Sr (˜5.8×10-2) isotope. Therefore, it is important to check if there is any variation of the stable strontium isotope ratio (88Sr/86Sr) in environmental samples after a nuclear accident.
Thermal ionization mass spectrometry is the technique of choice because of its inherent high precision and accurate measurement of isotopic ratio. Typical abundance sensitivity for strontium isotope ratio measurement with conventional TIMS is about 10-7. By the use of special lense like WARP filter for TIMS, an upper limit of 1.0 x 10-10 was achieved. Recent developments in analytical techniques have resulted in use of TIMS as a substitute for  counting method of strontium. In our laboratory, a Phoenix X62 TIMS has been set up with nine Farday cup collectors as well as Daly ion counting system to measure minor isotopes e.g. 90Sr. The range of the tested 90Sr activity varied from 0.12 mBq to 660 mBq. Isotope ratios of 90Sr as well as stable Sr isotope ratios in a few contaminated soil samples with radiocaesium and some plants from Fukushima prefecture will be presented.
会議概要(会議名, 開催地, 会期, 主催者等)
内容記述タイプ Other
内容記述 21st International Mass Spectrometry Conference (IMSC 2016)
発表年月日
日付 2016-08-26
日付タイプ Issued
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