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Alkaline Durable Anion-Conducting Electrolyte Membranes Prepared by Radiation Induced Grafting of 2-Methyl-4-vinylimidazole for Non-Platinum Direct Hydrazine Hydrate Fuel Cells
https://repo.qst.go.jp/records/54883
https://repo.qst.go.jp/records/54883bd8aedc1-9769-4966-bf1d-dd8f7cd4e4dc
| Item type | 会議発表論文 / Conference Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-04-15 | |||||
| タイトル | ||||||
| タイトル | Alkaline Durable Anion-Conducting Electrolyte Membranes Prepared by Radiation Induced Grafting of 2-Methyl-4-vinylimidazole for Non-Platinum Direct Hydrazine Hydrate Fuel Cells | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_5794 | |||||
| 資源タイプ | conference paper | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
前川, 康成
× 前川, 康成× 吉村, 公男× 竹内, 航太× 廣木, 章博× 渡邊, 俊× 萩原, 時男× 猪谷, 秀幸× 山口, 進× 田中, 裕久× 前川 康成× 吉村 公男× 竹内 航太× 廣木 章博× 猪谷 秀幸 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | For Pt-free alkaline-type fuel cells, anion-conducting polymer electrolyte membranes (AEMs) having a weak base imidazolium group, which scarcely damages the polymer backbones, have been developed. To prevent ring opening hydrolysis and β-elimination reactions, which are the main degradation routes, we conducted the radiation-induced grafting of 2-methyl-4(5)-vinylimidazole (2Me4VIm), which possesses methyl protecting group at imidazole C2 position and no b-protons, with styrene into a poly(ethylene-cotetrafluoro-ethylene) (ETFE) film and subsequent N-alkylation and ion exchange reactions to obtain 2Me4VIm/St-AEM (Im/St = 75/25) with ion exchange capacity of 1.35 mmol g-1. The conductivity and water uptake are 157 mS cm-1 and 86%, respectively. In 1 M KOH at 80°C, the initial rapid decrease of conductivity was clearly suppressed; then, the membrane maintained the conductivity above 15 mS/cm until 600 h. The semi-logarithmic plots of conductivity show 1st order kinetics, indicating the no b-elimination but only slow ring-opening hydrolysis in the alkaline condition. |
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| 書誌情報 |
ECS Transactions 巻 80, 号 8, p. 979-987, 発行日 2017-09 |
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| 出版者 | ||||||
| 出版者 | The Electrochemical Society | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1149/08008.0979ecst | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://ecst.ecsdl.org/content/80/8/979.abstract | |||||
| 関連名称 | http://ecst.ecsdl.org/content/80/8/979.abstract | |||||
