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ICP-MS analysis of environmental plutonium.
https://repo.qst.go.jp/records/52990
https://repo.qst.go.jp/records/529900074c5a3-6014-4ab4-bc9c-76f17da7c5a3
| Item type | 会議発表論文 / Conference Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2003-01-23 | |||||
| タイトル | ||||||
| タイトル | ICP-MS analysis of environmental plutonium. | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_5794 | |||||
| 資源タイプ | conference paper | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
Muramatsu, Yasuyuki
× Muramatsu, Yasuyuki× Yoshida, Satoshi× Tagami, Keiko× Uchida, Shigeo× Ruehm, Werner× 村松 康行× 吉田 聡× 田上 恵子× 内田 滋夫 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | ICP-MS was applied to determine the concentration of 239Pu and 240Pu and their isotope ratio in environmental samples. Two types of chromatographic resins, Dowex 1X8 and TEVA, were examined for their applicability to the separation of Pu from the matrix elements. Sufficient decontamination factors (104 - 105) for many matrix elements including U, which interferes with the detection of mass 239, were obtained with both resins. The detection limit of Pu by quadrupole-type ICP-MS was about 0.02 pg ml-1 in the sample solution. High resolution-type ICP-MS was also tested for its sensitivity and the detection limit was found to be about one order of magnitude better than this value. Analytical results of 239+240Pu in standard reference materials (IAEA-134, -135, -367, -368 and -SOIL-6) indicated that the accuracy of the method was satisfactory. Data on the 240Pu/239Pu atom ratios in these reference materials, which are scarce in the literature, were also obtained. Compared with alpha-spectrometry, the ICP-MS method has significant advantages in terms of prompt measurement time, simple analytical procedures and capability of determining the 240Pu/239Pu ratio. The 240Pu/239Pu atom ratios observed in seven soil samples collected from different places in Japan ranged from 0.168 to 0.181, which are comparable to the global fallout ratio. Analytical results for samples originating from different places worldwide (including contaminated areas) showed a wide range of the 240Pu/239Pu atom ratio (0.04 - 0.4) according to the source of the Pu. Determination of the 240Pu/239Pu ratio is useful to identify the origin of the contamination. | |||||
| 書誌情報 |
Plutonium in the Environment (Radioactivity in the Environment ; v. 1) p. 63-77, 発行日 2001 |
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| 出版者 | ||||||
| 出版者 | Elsevier | |||||
