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Elucidation of the Two-Step Damage Formation Process of Latent Tracks in Poly(allyl diglycol carbonate), PADC: Role of Secondary Low-Energy Electrons
https://repo.qst.go.jp/records/49180
https://repo.qst.go.jp/records/491807bad446c-de33-4bf6-9a65-727fb74b192e
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-08-24 | |||||
タイトル | ||||||
タイトル | Elucidation of the Two-Step Damage Formation Process of Latent Tracks in Poly(allyl diglycol carbonate), PADC: Role of Secondary Low-Energy Electrons | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Kusumoto, Tamon
× Kusumoto, Tamon× Fromm, Michel× Cloutier, Pierre× D. Bass, Andrew× Sanche, Leon× Rémi, Barillon× Yamauchi, Tomoya× Kusumoto, Tamon |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The aim of the present study is to evaluate the mechanisms by which secondary electrons of low energy degrade poly(allyl diglycol carbonate) (PADC) when it is used as a Solid State Nuclear Track Detector. We measured, by time-of-flight mass spectrometry, the positive and negative ions desorbed by the impact of 5−30 eV electrons on three monolayer thick films of various PADC surrogate molecules, which contained ether and/or carbonyl (CO) moieties. As cleavages within the molecules progress, most anion yields are seen to decrease with an increasing cumulative number of incident electrons (i.e., fluence). In contrast, the yield of O− at incident energies >15 eV, which is associated with damage at a carbonyl group, increases monotonically with fluence. This finding implies that cleavage of carbonyl groups occurs after damage to other oxygen containing groups within the surrogates. The present result corroborates the previously postulated two- step degradation process in PADC irradiated with high-energy electrons and 222 nm UV photons. More generally, these results underline the importance of considering the role of low energy secondary electrons in the deterioration of high-sensitivity energetic particle detectors. | |||||
書誌情報 |
The Journal of Physical Chemistry C 巻 122, 号 36, p. 21056-21061, 発行日 2018-08 |
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出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1932-7447 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/acs.jpcc.8b05341 | |||||
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識別子タイプ | URI | |||||
関連識別子 | https://pubs.acs.org/doi/ipdf/10.1021/acs.jpcc.8b05341 |