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Water-Accelerated Radical-Scavenging Reaction of (+)-Catechin in an Aprotic Medium
https://repo.qst.go.jp/records/48559
https://repo.qst.go.jp/records/4855985a7761f-816c-40bd-abf1-0c1eae11a5ce
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-03-08 | |||||
タイトル | ||||||
タイトル | Water-Accelerated Radical-Scavenging Reaction of (+)-Catechin in an Aprotic Medium | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Nakanishi, Ikuo
× Nakanishi, Ikuo× Kawashima, Tomonori× Fukuhara, Kiyoshi× Kanazawa, Hideko× Okuda, Haruhiro× Fukuzumi, Shunichi× Ozawa, Toshihiko× Ikota, Nobuo× 中西 郁夫× 川島 知憲× 小澤 俊彦× 伊古田 暢夫 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The scavenging reaction of galvinoxyl radical by (+)-catechin in deaerated acetonitrile, which is reported to proceed via an electron transfer from (+)-catechin to galvinoxyl radical to produce catechin radical cation and galvinoxyl anion followed by proton transfer, was significantly accelerated by the addition of water. The strong solvation of water to the catechin radical cation may result in the largely negative shift of the one-electron oxidation potential of (+)-catechin, resulting in the acceleration of the initial electron-transfer oxidation of (+)-catechin by galvinoxyl radical. | |||||
書誌情報 |
ITE Letters on Batteries, New Technologies & Medicine 巻 5, 号 6, p. 585-588, 発行日 2004-12 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1531-2046 |