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  1. 原著論文

Application of laser-induced breakdown spectroscopy to zirconium in aqueous solution

https://repo.qst.go.jp/records/47932
https://repo.qst.go.jp/records/47932
7fc148d9-1a98-4250-9e4a-8ebbba4260c6
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-05-02
タイトル
タイトル Application of laser-induced breakdown spectroscopy to zirconium in aqueous solution
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Ruas, Alexandre

× Ruas, Alexandre

WEKO 481224

Ruas, Alexandre

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松本, 歩

× 松本, 歩

WEKO 481225

松本, 歩

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大場, 弘則

× 大場, 弘則

WEKO 481226

大場, 弘則

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赤岡, 克昭

× 赤岡, 克昭

WEKO 481227

赤岡, 克昭

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若井田, 育夫

× 若井田, 育夫

WEKO 481228

若井田, 育夫

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大場 弘則

× 大場 弘則

WEKO 481229

en 大場 弘則

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内容記述タイプ Abstract
内容記述 In the context of the Fukushima Dai-ichi Nuclear Power Plant (F1-NPP) decommissioning process, laser-induced breakdown spectroscopy (LIBS) has many advantages. The purpose of the present work is to demonstrate the on-line monitoring capability of the LIBS coupled with the ultra-thin liquid jet sampling method. The study focuses on zirconium in aqueous solution, considering that it is a major element in the F1-NPP fuel debris that has been subject to only a few LIBS studies in the past. The methodology of data acquisition and processing are described. In particular, two regions of interest with many high intensity zirconium lines have been observed around 350 nm in the case of the ionic lines and 478 nm in the case of atomic lines. The best analytical conditions for zirconium are different depending on the analysis of ionic lines or atomic lines. A low LOD of about 4 mg L− 1 could be obtained, showing that LIBS coupled with the ultra-thin liquid jet sampling technique is a promising alternative for more complex solutions found in the F1-NPP, namely mixtures containing zirconium.
書誌情報 Spectrochimica Acta Part B: Atomic Spectroscopy

巻 131, p. 99-106, 発行日 2017-05
出版者
出版者 ELSEVIER
DOI
識別子タイプ DOI
関連識別子 10.1016/j.sab.2017.03.014
関連サイト
識別子タイプ URI
関連識別子 http://www.sciencedirect.com/science/article/pii/S0584854716303846
関連名称 http://www.sciencedirect.com/science/article/pii/S0584854716303846
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