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Isotopic effect in the (2+1) REMPI spectra of 13C-substituted methyl iodide for UV selective dissociation
https://repo.qst.go.jp/records/46202
https://repo.qst.go.jp/records/46202e758767d-cfca-43be-9813-279ded7641d1
| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2011-11-09 | |||||
| タイトル | ||||||
| タイトル | Isotopic effect in the (2+1) REMPI spectra of 13C-substituted methyl iodide for UV selective dissociation | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
| 著者 |
Wakai, Atsushi
× Wakai, Atsushi× Tsuchida, Kazuki× Fukumura, Toshimitsu× Suzuki, Kazutoshi× 若井 篤志× 土田 一輝× 福村 利光× 鈴木 和年 |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | To investigate a possible means of achieving isotopic enrichment of methyl iodide (CH3I), we studied the 6s Rydberg states of 13,12CH3I by (2 + 1) resonance-enhanced multiphoton ionization. For band (v3 hot band) excitation (at a full width at half maximum of 14 cm−1), we observed a well-resolved isotope shift of +16 cm−1. The band shape, which has a broad shoulder on the red side and an abrupt decrease on the blue side, indicates that this resonance is ideal for enriching the concentration of the desired lighter isotope (the isotopomer). | |||||
| 書誌情報 |
Chemical Physics Letters 巻 516, 号 1/3, p. 23-28, 発行日 2011-10 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0009-2614 | |||||
