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Precise Size Control and Synchronized Synthesis of Six Colors of CdSe Quantum Dots at a Slow-Increasing Temperature Gradient
https://repo.qst.go.jp/records/45129
https://repo.qst.go.jp/records/451294de3ed28-0531-4a85-a49e-d09d6d9d7917
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-03-25 | |||||
タイトル | ||||||
タイトル | Precise Size Control and Synchronized Synthesis of Six Colors of CdSe Quantum Dots at a Slow-Increasing Temperature Gradient | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Zlateva, Genoveva
× Zlateva, Genoveva× Zhelev, Zhivko× Bakalova-Zheleva, Rumiana× Kanno, Iwao× バカロバ ルミアナ× 菅野 巖 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The present study describes a simultaneous and highly reproducible large-scale synthesis of six (and more) colors of size-homogeneous and highly luminescent CdSe quantum dots in a single reaction, controlled by a slow-increasing temperature gradient. The described protocol allows a precise control and a synchronized isolation of aliquots of CdSe nanocrystals with defined sizes, avoiding disturbance of the growth of nanocrystals (existing in the reaction mixture) to the isolation of the next aliquot. The obtained quantum dot fractions are of high quality (in 95% size-homogeneous) and have sharp photoluminescence spectra (fwhm ~ 30 nm), quantum yields of 45-70% (in organic solvent), and a lack of aggregation in organic solvents. The method is environmentally friendly as it ensures almost complete utilization of the precursors and productive yield ~95%. | |||||
書誌情報 |
Inorganic Chemistry 巻 46, 号 16, p. 6212-6214, 発行日 2007-06 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0020-1669 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/ic062045s |