| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-11-11 |
| タイトル |
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タイトル |
Study on photodissociation spectra and decay pathways of gas-phase PdCl3? and PdCl2? anions by electrospray ionization mass spectrometry and MRCI calculation |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
小山雅大
Kurosaki Yuzuru
黒崎
村松悟
Saeki Morihisa
佐伯
井口佳哉
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
We investigate photodissociation of the gas-phase palladium complex anions, Pd(II)Cl3- and Pd(I)Cl2-, both experimentally and theoretically. Visible photodissociation mass spectrometry reveals that the main dissociation channels differ for Pd(II)Cl3- and Pd(I)Cl2-; the former yields neutral chlorine atom (Pd(I)Cl2- + Cl) whereas the latter affords chloride anion (Pd(I)Cl + Cl-). Absorption spectrum and photodissociation channels are predicted using the MRCI method. The observed absorption spectrum and dissociation product for Pd(II)Cl3- agree with the MRCI calculation, whereas those for Pd(I)Cl2- do not, which suggests that some relaxation process such as internal conversion significantly contributes to the photodissociation of Pd(I)Cl2-. |
| 書誌情報 |
Chemical Physics Letters
巻 857,
p. 141736,
発行日 2024-12
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| 出版者 |
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出版者 |
ELSEVIER |
| DOI |
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識別子タイプ |
DOI |
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関連識別子 |
10.1016/j.chemphys.2024.112182 |
