| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-04-17 |
| タイトル |
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タイトル |
Increase of OH radical yields due to the decomposition of hydrogen peroxide by gold nanoparticles under X-ray irradiation |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
Yu Okazaki
Kusumoto Tamon
Stephane Roux
Hirayama Ryoichi
Michel Fromm
Rana Bazzi
Kodaira Satoshi
Jun Kataoka
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
We address to elucidate the decomposition mechanism of hydrogen peroxide, which is formed by water radiolysis, by gold nanoparticles (GNPs) under X-ray irradiation. The variations in yields of hydrogen peroxide generated in the presence of GNPs are evaluated using the Ghormley technique. The increase of yields of OH radicals has been quantified using AmplifluR Red solutions. Almost all hydrogen peroxide generated by irradiation of < 25 Gy is decomposed by GNPs, while the yield of OH radicals increases by 1.6 times. The amount of OH radicals thus obtained is almost equivalent to that of the decomposed hydrogen peroxide. The decomposition of hydrogen peroxide is an essential reaction to produce additional OH radicals efficiently in the vicinity of GNPs. |
| 書誌情報 |
RSC Advances
号 14,
p. 9509-9513,
発行日 2024-04
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| 出版者 |
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出版者 |
The Royal Society of Chemistry |
| DOI |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1039/D4RA00208C |