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Mixing time of homogeneous/heterogeneous solutions in a micro-mixer with free impinging jets
https://repo.qst.go.jp/records/2000683
https://repo.qst.go.jp/records/200068318619ab3-d30e-4e3d-9187-c4e8fa645109
| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||||||
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| 公開日 | 2024-12-06 | |||||||||
| タイトル | ||||||||||
| タイトル | Mixing time of homogeneous/heterogeneous solutions in a micro-mixer with free impinging jets | |||||||||
| 言語 | en | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| 著者 |
Endo Tomoyuki
× Endo Tomoyuki
× Itakura Ryuji
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| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | We have developed a micro-mixer based on a free impinging liquid-sheet jet technique. We identified a mixing position where two different solutions mixed uniformly and evaluated a corresponding mixing time in the liquid-sheet jets with homogeneous combination (H2O and H2O) and heterogeneous combination (C2H5OH and H2O). By observing a quenching reaction, the mixing times were evaluated to be 36 μs for the homogeneous combination (H2O/H2O), and 46 μs for the heterogeneous combination (C2H5OH/H2O). To clarify the mixing mechanism in the liquid-sheet jet, the theoretical mixing times were calculated by two different models assuming laminar and turbulence flows. The calculated mixing times based on energy dissipation in the turbulence flow are in great agreement with the observed mixing times for both H2O/H2O and C2H5OH/H2O combinations. These results indicate that turbulent mixing is a dominant mixing mechanism in the liquid-sheet jet, and that no clear interface is formed between H2O solutions and between C2H5OH and H2O solutions. The liquid-sheet jet technique provides a windowless and ultra-thin target and would be useful to investigate intermediates in mixing-driven chemical reactions such as an oxidation in solution and a folding reaction of proteins proceeding in a microsecond time scale. | |||||||||
| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 97, 号 2, p. uoad021, 発行日 2023-12 |
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| 出版者 | ||||||||||
| 出版者 | Oxford University Press | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 0009-2673 | |||||||||
| DOI | ||||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.1093/bulcsj/uoad021 | |||||||||