| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-08-08 |
| タイトル |
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タイトル |
X-ray irradiation-induced ligand cleavage of a phthalocyanine derivative, tin (IV) phthalocyanine dichloride: A potential for X-ray activation of caged compounds |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
Izumi Yudai
Ohara Maki
Fujii Kentaro
Yokoya Akinari
Mikako Ogawa
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| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The X-ray dissociation of tin (IV) phthalocyanine dichloride (SnCl2Pc) was investigated using X-ray photoemission spectroscopy. The photoemission spectra of SnCl2Pc after X-ray irradiation exhibited additional components assigned as chloride ions and tin (II) phthalocyanine, as well as decomposition products from the phthalocyanine framework, indicating that X-ray irradiation induced the release of chloride ions as ligands from SnCl2Pc. Although the ligand releases were caused not by a simple cleavage between Cl-Sn bonding but by accompanying the molecular framework destruction, these reactions may robustly facilitate a novel application of X-rays to activate caged compounds in tissues. |
| 書誌情報 |
Chemical Physics Letters
巻 822,
p. 140508,
発行日 2023-04
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| 出版者 |
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出版者 |
Elsevier |
| ISSN |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0009-2614 |
| DOI |
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識別子タイプ |
DOI |
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関連識別子 |
10.1016/j.cplett.2023.140508 |
