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  1. 原著論文

Elucidation of the Two-Step Damage Formation Process of Latent Tracks in Poly(allyl diglycol carbonate), PADC: Role of Secondary Low-Energy Electrons

https://repo.qst.go.jp/records/49180
https://repo.qst.go.jp/records/49180
7bad446c-de33-4bf6-9a65-727fb74b192e
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-08-24
タイトル
タイトル Elucidation of the Two-Step Damage Formation Process of Latent Tracks in Poly(allyl diglycol carbonate), PADC: Role of Secondary Low-Energy Electrons
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Kusumoto, Tamon

× Kusumoto, Tamon

WEKO 747834

Kusumoto, Tamon

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Fromm, Michel

× Fromm, Michel

WEKO 747835

Fromm, Michel

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Cloutier, Pierre

× Cloutier, Pierre

WEKO 747836

Cloutier, Pierre

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D. Bass, Andrew

× D. Bass, Andrew

WEKO 747837

D. Bass, Andrew

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Sanche, Leon

× Sanche, Leon

WEKO 747838

Sanche, Leon

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Rémi, Barillon

× Rémi, Barillon

WEKO 747839

Rémi, Barillon

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Yamauchi, Tomoya

× Yamauchi, Tomoya

WEKO 747840

Yamauchi, Tomoya

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Kusumoto, Tamon

× Kusumoto, Tamon

WEKO 747841

en Kusumoto, Tamon

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内容記述タイプ Abstract
内容記述 The aim of the present study is to evaluate the mechanisms by which secondary electrons of low energy degrade poly(allyl diglycol carbonate) (PADC) when it is used as a Solid State Nuclear Track Detector. We measured, by time-of-flight mass spectrometry, the positive and negative ions desorbed by the impact of 5−30 eV electrons on three monolayer thick films of various PADC surrogate molecules, which contained ether and/or carbonyl (CO) moieties. As cleavages within the molecules progress, most anion yields are seen to decrease with an increasing cumulative number of incident electrons (i.e., fluence). In contrast, the yield of O− at incident energies >15 eV, which is associated with damage at a carbonyl group, increases monotonically with fluence. This finding implies that cleavage of carbonyl groups occurs after damage to other oxygen containing groups within the surrogates. The present result corroborates the previously postulated two- step degradation process in PADC irradiated with high-energy electrons and 222 nm UV photons. More generally, these results underline the importance of considering the role of low energy secondary electrons in the deterioration of high-sensitivity energetic particle detectors.
書誌情報 The Journal of Physical Chemistry C

巻 122, 号 36, p. 21056-21061, 発行日 2018-08
出版者
出版者 American Chemical Society
ISSN
収録物識別子タイプ ISSN
収録物識別子 1932-7447
DOI
識別子タイプ DOI
関連識別子 10.1021/acs.jpcc.8b05341
関連サイト
識別子タイプ URI
関連識別子 https://pubs.acs.org/doi/ipdf/10.1021/acs.jpcc.8b05341
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