{"created":"2023-05-15T15:03:09.014243+00:00","id":85547,"links":{},"metadata":{"_buckets":{"deposit":"0bb349a3-4740-490a-9c93-00e3ec0c3fb2"},"_deposit":{"created_by":1,"id":"85547","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"85547"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00085547","sets":["1"]},"author_link":["1036910","1036911","1036912","1036913","1036914"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"417","bibliographicPageStart":"409","bibliographicVolumeNumber":"38","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"X-ray diffraction measurements are performed on a 1 m (=mol kg−1) CeCl3 aqueous solution over a temperature range of 300–600 K and a pressure range of 0.1 MPa to 4 GPa. The experimental interference functions are analyzed by an empirical potential structure refinement (EPSR) modeling. The Ce3+ coordinates water molecules in a tricapped trigonal prism configuration under the ambient condition. The number of water molecules around Ce3+ changes from 8.8 at 0.1 MPa/300 K to 11.5 at 4 GPa/600 K. The number of water molecules around Cl− changes drastically from 10 under the ambient condition \nto 17 at 4 GPa/600 K. The tetrahedral-like network structure of water under the ambient condition is transformed toward a simple liquid-like packing in the GPa pressure range. The corresponding coordination number is increased from 4.3 in the ambient condition to 9.7 at 4 GPa/600 K. The Ce3+–Cl− association decreases with increasing pressure.","subitem_description_type":"Abstract"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.2116/analsci.21P297","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://link.springer.com/article/10.2116/analsci.21P297","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamaguchi, Toshio"}],"nameIdentifiers":[{"nameIdentifier":"1036910","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuyama, Nami"}],"nameIdentifiers":[{"nameIdentifier":"1036911","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshida, Koji"}],"nameIdentifiers":[{"nameIdentifier":"1036912","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Katayama, Yoshinori"}],"nameIdentifiers":[{"nameIdentifier":"1036913","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshinori, Katayama","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1036914","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Ion solvation and association and water structure in an aqueous cerium(III)chloride solution in the gigapascal pressure range","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ion solvation and association and water structure in an aqueous cerium(III)chloride solution in the gigapascal pressure range"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-03-14"},"publish_date":"2022-03-14","publish_status":"0","recid":"85547","relation_version_is_last":true,"title":["Ion solvation and association and water structure in an aqueous cerium(III)chloride solution in the gigapascal pressure range"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T17:31:02.217006+00:00"}