{"created":"2023-05-15T15:02:26.715255+00:00","id":84671,"links":{},"metadata":{"_buckets":{"deposit":"2a5d754a-5b50-4083-b4f5-2522795e6e24"},"_deposit":{"created_by":1,"id":"84671","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"84671"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00084671","sets":["1"]},"author_link":["1021897","1021898","1021899","1021896"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-12","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"107190","bibliographicVolumeNumber":"134","bibliographic_titles":[{"bibliographic_title":"Electrochemistry Communications"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"2,2-Diphenyl-1-picrylhydrazyl (DPPH) radical is a water-insoluble stable radical that has been used to evaluate the activity of antioxidants as a reactivity model of reactive oxygen species. In this work, the cyclic voltammetry of the DPPH radical solubilized in water by complexation with beta-cyclodextrin was studied in phosphate buffer solutions (0.1 M, pH 6.0, 7.0, and 8.0). The DPPH radical undergoes a reversible proton-coupled reduction, where the half-wave potential linearly shifts to the negative direction as the solution pH increases. On the other hand, the cyclic voltammogram of the oxidation of the DPPH radical is quasi-reversible, indicating that the oxidized product of the DPPH radical undergoes a chemical reaction.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.elecom.2021.107190","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.sciencedirect.com/science/article/pii/S1388248121002745","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1388-2481","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakanishi, Ikuo"}],"nameIdentifiers":[{"nameIdentifier":"1021896","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shoji, Yoshimi"}],"nameIdentifiers":[{"nameIdentifier":"1021897","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ikuo, Nakanishi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1021898","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshimi, Shoji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1021899","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electrochemical Redox Behavior of 2,2-Diphenyl-1-picrylhydrazyl Radical Solubilized by β-Cyclodextrin in Water","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electrochemical Redox Behavior of 2,2-Diphenyl-1-picrylhydrazyl Radical Solubilized by β-Cyclodextrin in Water"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-12-23"},"publish_date":"2021-12-23","publish_status":"0","recid":"84671","relation_version_is_last":true,"title":["Electrochemical Redox Behavior of 2,2-Diphenyl-1-picrylhydrazyl Radical Solubilized by β-Cyclodextrin in Water"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T18:16:31.373481+00:00"}