{"created":"2023-05-15T15:00:09.721705+00:00","id":81645,"links":{},"metadata":{"_buckets":{"deposit":"e32b09c8-3d65-4bf1-9fe2-b61faab76074"},"_deposit":{"created_by":1,"id":"81645","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"81645"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00081645","sets":["1"]},"author_link":["1015519","1015516","1015517","1015515","1015514","1015520","1015518","1015521"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"531","bibliographicPageStart":"523","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"Polymer Journal"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Poly(methacrylated vanillin) (PMV) was investigated for its reactivity in multicomponent reactions as a reactive polymer that can be sourced from lignin-based components. To achieve sustainable polymer chemistry, the PMV reactivity in a Passerini three-component reaction (Passerini-3CR) was investigated because the reactants in the Passerini-3CR can be abundantly sourced from biobased compounds. First, the Passerini-3CR of the PMV in solution phases revealed that the PMV pendant aldehydes can be converted into the corresponding α-acyloxy amides with >90% conversions under the optimized conditions. Taking advantage of this high reactivity of PMV, its immobilized cellulose fabric (Cell-g-PMV), a wood biomass-sourced organic hybrid, was subjected to the Passerini-3CR. Although the aldehydes were not completely converted, the PMV segments surrounding the fabric surfaces successfully reacted via the Passerini-3CR to engraft carboxylic acid and isocyanide components on the cellulose-based fabrics.","subitem_description_type":"Abstract"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1038/s41428-020-00448-w","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.nature.com/articles/s41428-020-00448-w","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0032-3896","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kakuchi, Ryohei"}],"nameIdentifiers":[{"nameIdentifier":"1015514","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tsuji, Ryota"}],"nameIdentifiers":[{"nameIdentifier":"1015515","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukasawa, Kota"}],"nameIdentifiers":[{"nameIdentifier":"1015516","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Shuhei"}],"nameIdentifiers":[{"nameIdentifier":"1015517","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Omichi, Masaaki"}],"nameIdentifiers":[{"nameIdentifier":"1015518","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Seko, Noriaki"}],"nameIdentifiers":[{"nameIdentifier":"1015519","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Masaaki, Omichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1015520","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Noriaki, Seko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1015521","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Polymers of lignin-sourced components as a facile chemical integrant for the Passerini three-component reaction","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Polymers of lignin-sourced components as a facile chemical integrant for the Passerini three-component reaction"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-01-12"},"publish_date":"2021-01-12","publish_status":"0","recid":"81645","relation_version_is_last":true,"title":["Polymers of lignin-sourced components as a facile chemical integrant for the Passerini three-component reaction"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T18:43:09.488923+00:00"}