@article{oai:repo.qst.go.jp:00081645,
 author = {Kakuchi, Ryohei and Tsuji, Ryota and Fukasawa, Kota and Yamashita, Shuhei and Omichi, Masaaki and Seko, Noriaki and Masaaki, Omichi and Noriaki, Seko},
 journal = {Polymer Journal},
 month = {Jan},
 note = {Poly(methacrylated vanillin) (PMV) was investigated for its reactivity in multicomponent reactions as a reactive polymer that can be sourced from lignin-based components. To achieve sustainable polymer chemistry, the PMV reactivity in a Passerini three-component reaction (Passerini-3CR) was investigated because the reactants in the Passerini-3CR can be abundantly sourced from biobased compounds. First, the Passerini-3CR of the PMV in solution phases revealed that the PMV pendant aldehydes can be converted into the corresponding α-acyloxy amides with >90% conversions under the optimized conditions. Taking advantage of this high reactivity of PMV, its immobilized cellulose fabric (Cell-g-PMV), a wood biomass-sourced organic hybrid, was subjected to the Passerini-3CR. Although the aldehydes were not completely converted, the PMV segments surrounding the fabric surfaces successfully reacted via the Passerini-3CR to engraft carboxylic acid and isocyanide components on the cellulose-based fabrics.},
 pages = {523--531},
 title = {Polymers of lignin-sourced components as a facile chemical integrant for the Passerini three-component reaction},
 volume = {53},
 year = {2021}
}