{"created":"2023-05-15T14:58:59.573257+00:00","id":80037,"links":{},"metadata":{"_buckets":{"deposit":"a2f6ee65-4e12-45d5-81b6-1f09b286ee5c"},"_deposit":{"created_by":1,"id":"80037","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"80037"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00080037","sets":["1"]},"author_link":["907231","907228","907229","907230","907232","907233","907227","907225","907226"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"35","bibliographicVolumeNumber":"137","bibliographic_titles":[{"bibliographic_title":"Journal of Applied Polymer Science"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The hierarchical structures of poly(styrenesulfonic acid)-grafted poly(ethylene-co-tetrafluoroethylene)　polymer electrolyte membrane (ETFE-PEM) with different scale ranges including lamellar spacing, interfacial　thickness, and intra-structure of conducting layers consisting of graft-polymers and water were evaluated by　SAXS in terms of background scattering (IB(q)). First, IB(q) was roughly estimated by modifying Ruland’s　method and then optimized to avoid overestimation using a “contribution factor”, which is defined as the　contribution of IB(q) to the observed scattering intensities over the entire q range. Then, IB(q) was optimized　again by using Ruland’s equation to select proper q-range for interfacial thickness evaluation. The lamellar　spacing, which is observed in the low-q range, was not altered by background correction. In contrast, in the　high-q range, the interfacial thickness and the internal structures of the conducting layers can be estimated only　after correction for the background scattering data. These results clearly show that the hierarchical structures　of graft-type PEMs were strongly affected by the background correction in the high-q range. Moreover, the　proposed procedure for IB(q) is crucial for the determination of accurate interfacial thickness but not intrastructure　of conducting layers. Note that the modified Ruland’s method can be used as an altermative method　for determination of background intensity.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/app.49029","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://onlinelibrary.wiley.com/doi/abs/10.1002/app.49029","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-8995","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Duy Tap, Tran"}],"nameIdentifiers":[{"nameIdentifier":"907225","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ly Nguyen, La"}],"nameIdentifiers":[{"nameIdentifier":"907226","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hasegawa, Shin"}],"nameIdentifiers":[{"nameIdentifier":"907227","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sawada, Shinichi"}],"nameIdentifiers":[{"nameIdentifier":"907228","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Quang Luan, Le"}],"nameIdentifiers":[{"nameIdentifier":"907229","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maekawa, Yasunari"}],"nameIdentifiers":[{"nameIdentifier":"907230","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hasegawa, Shin","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"907231","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sawada, Shinichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"907232","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maekawa, Yasunari","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"907233","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Internal and interfacial structure analysis of graft-type fluorinated polymer electrolyte membrane by smallangle X-ray scattering in the high-q range","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Internal and interfacial structure analysis of graft-type fluorinated polymer electrolyte membrane by smallangle X-ray scattering in the high-q range"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-01-23"},"publish_date":"2020-01-23","publish_status":"0","recid":"80037","relation_version_is_last":true,"title":["Internal and interfacial structure analysis of graft-type fluorinated polymer electrolyte membrane by smallangle X-ray scattering in the high-q range"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T21:08:42.465126+00:00"}