{"created":"2023-05-15T14:58:19.708578+00:00","id":79122,"links":{},"metadata":{"_buckets":{"deposit":"d657735c-e31e-4516-9aa7-20a36066d342"},"_deposit":{"created_by":1,"id":"79122","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"79122"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00079122","sets":["1"]},"author_link":["1000283","1000280","1000287","1000281","1000290","1000284","1000288","1000277","1000278","1000279","1000276","1000286","1000289","1000282","1000275","1000274","1000285"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"2764","bibliographicPageStart":"2758","bibliographicVolumeNumber":"59","bibliographic_titles":[{"bibliographic_title":"Inorganic Chemistry"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Mgベースの遷移金属水素化物は安価で重量水素密度および体積水素密度が高いため、注目されている水素貯蔵材料である。しかながら、それらのほとんどは安定であり、適度な条件下で水素を放出することが困難であるという課題がある。我々は同じ立方構造のMg2FeH6とMg2Siで構成されるMg2FexSi1-xの水素化物を合成した。Siリッチの水素化物（x <0.5）ではX線回折でMg2Si相のみが観察されるが、メスバウアー分光法ではFeH6の形成が示唆され、また、TEM観察とPDF解析によりナノメートルサイズのMg2FeH6ドメインがMg2Siマトリックスに形成されていることが示唆された。この金属組織構造によりMg2FeH6ユニットセルの体積が減少した結果、熱的に不安定になったと考えられる。\n","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.inorgchem.9b03117","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b03117","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0020-1669","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Asano, Kohta"}],"nameIdentifiers":[{"nameIdentifier":"1000274","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kim, Hyunjeong"}],"nameIdentifiers":[{"nameIdentifier":"1000275","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakaki, Kouji"}],"nameIdentifiers":[{"nameIdentifier":"1000276","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakamura, Yumiko"}],"nameIdentifiers":[{"nameIdentifier":"1000277","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wang, Yongming"}],"nameIdentifiers":[{"nameIdentifier":"1000278","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Isobe, Shigehito"}],"nameIdentifiers":[{"nameIdentifier":"1000279","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Doi, Masaaki"}],"nameIdentifiers":[{"nameIdentifier":"1000280","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fujita, Asaya"}],"nameIdentifiers":[{"nameIdentifier":"1000281","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maejima, Naoyuki"}],"nameIdentifiers":[{"nameIdentifier":"1000282","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Machida, Akihiko"}],"nameIdentifiers":[{"nameIdentifier":"1000283","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanuki, Tetsu"}],"nameIdentifiers":[{"nameIdentifier":"1000284","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"J. Westerwaal, Ruud"}],"nameIdentifiers":[{"nameIdentifier":"1000285","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Schreuders, Herman"}],"nameIdentifiers":[{"nameIdentifier":"1000286","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Dam, Bernard"}],"nameIdentifiers":[{"nameIdentifier":"1000287","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Naoyuki, Maejima","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1000288","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Akihiko, Machida","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1000289","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tetsu, Watanuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1000290","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Metallurgical Synthesis of Mg2FexSi1-x Hydride: Destabilization of Mg2FeH6 Nanoconfined in Templated Mg2Si","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Metallurgical Synthesis of Mg2FexSi1-x Hydride: Destabilization of Mg2FeH6 Nanoconfined in Templated Mg2Si"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-10-31"},"publish_date":"2019-10-31","publish_status":"0","recid":"79122","relation_version_is_last":true,"title":["Metallurgical Synthesis of Mg2FexSi1-x Hydride: Destabilization of Mg2FeH6 Nanoconfined in Templated Mg2Si"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T19:42:02.085576+00:00"}