{"created":"2023-05-15T14:57:39.110058+00:00","id":78244,"links":{},"metadata":{"_buckets":{"deposit":"fc9672ec-3e5c-48e0-8c5b-4fb301fbef09"},"_deposit":{"created_by":1,"id":"78244","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"78244"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00078244","sets":["10:28"]},"author_link":["819742","819736","819747","819740","819739","819748","819745","819746","819741","819743","819738","819737","819744"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2019-12-17","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"貴金属イオン水溶液にアルコールなどの還元助剤を添加し、紫外光を照射すると貴金属イオンが還元されて貴金属原子になり、水溶液中で自発的に凝集して貴金属微粒子を形成する（光誘起微粒子化）。この時、還元助剤以外に光増感剤（ベンゾインなど）を添加すると、紫外光吸収により生成するラジカルが貴金属イオンの還元を促進するので、ランプのような低強度の紫外光でも光誘起微粒子化を起こせる。一方、光増感剤を添加しない場合には、貴金属錯イオンが紫外領域に有する電荷移動吸収帯を励起してイオンを還元しなければならず、電荷移動帯の吸収係数は光増感剤よりも低いので、レーザーのような高強度の紫外光源を必要とする。本研究では、光増感剤を加えない、塩化パラジウムイオン（PdCl4^2–）の水/エタノール混合溶液に、紫外レーザー光を照射した時の光誘起微粒子化反応をDispersive XAFS（DXAFS）分光で調べたので報告する。","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"XAFS・X線顕微鏡分光分析分野でのIMSS, PF戦略的利用に関する研究会","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐伯, 盛久"}],"nameIdentifiers":[{"nameIdentifier":"819736","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松村, 大樹"}],"nameIdentifiers":[{"nameIdentifier":"819737","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"蓬田, 匠"}],"nameIdentifiers":[{"nameIdentifier":"819738","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"田口, 富嗣"}],"nameIdentifiers":[{"nameIdentifier":"819739","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"辻, 卓也"}],"nameIdentifiers":[{"nameIdentifier":"819740","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"齋藤, 寛之"}],"nameIdentifiers":[{"nameIdentifier":"819741","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西, 隆造"}],"nameIdentifiers":[{"nameIdentifier":"819742","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大場, 弘則"}],"nameIdentifiers":[{"nameIdentifier":"819743","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saeki, Morihisa","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"819744","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Taguchi, Tomitsugu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"819745","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saito, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"819746","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakanishi, Ryuzo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"819747","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Oba, Hironori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"819748","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"レーザー誘起パラジウム微粒子化反応のDXAFS研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"レーザー誘起パラジウム微粒子化反応のDXAFS研究"}]},"item_type_id":"10005","owner":"1","path":["28"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-12-16"},"publish_date":"2019-12-16","publish_status":"0","recid":"78244","relation_version_is_last":true,"title":["レーザー誘起パラジウム微粒子化反応のDXAFS研究"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:20:31.562247+00:00"}