{"created":"2023-05-15T14:56:04.646832+00:00","id":76157,"links":{},"metadata":{"_buckets":{"deposit":"8c15e654-fff2-4208-a474-d807288b4426"},"_deposit":{"created_by":1,"id":"76157","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"76157"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00076157","sets":["1"]},"author_link":["799442","799443","799441","799440"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1098(17)","bibliographicPageStart":"1098(1)","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"polymers"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"To determine the molecular weight of graft chains in grafted films, the polystyrene graft chains of PVDF–g–St films synthesized by a pre-irradiation graft method are cleaved and separated by boiling xylene extraction. The analysis of the extracted material and the residual films by FTIR, nuclear magnetic resonance (NMR), and gel permeation chromatography (GPC) analyses indicates that most graft chains are removed from the PVDF–g–St films within 72 h of extraction time. Furthermore, the molecular weight of the residual films decreases quickly within 8 h of extraction and then remains virtually unchanged up to 72 h after extraction time. The degradation is due to the cleavage of graft bonds, which is mainly driven by the thermal degradation and the swelling of graft chains in solution. This allows determination of the molecular weight of graft chains by GPC analysis of the extracted material. The results indicate that the PVDF–g–St prepared in this study has the structure where one or two graft chains hang from each PVDF backbone. ","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"MDPI"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3390/polym11071098","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.mdpi.com/2073-4360/11/7/1098","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2073-4360","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Jinhua, Chen"}],"nameIdentifiers":[{"nameIdentifier":"799440","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Seko, Noriaki"}],"nameIdentifiers":[{"nameIdentifier":"799441","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Jinhua, Chen","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"799442","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Seko, Noriaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"799443","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cleavage of the Graft Bonds in PVDF–g–St Films by Boiling Xylene Extraction and the Determination of the Molecular Weight of the Graft Chains ","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cleavage of the Graft Bonds in PVDF–g–St Films by Boiling Xylene Extraction and the Determination of the Molecular Weight of the Graft Chains "}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-07-01"},"publish_date":"2019-07-01","publish_status":"0","recid":"76157","relation_version_is_last":true,"title":["Cleavage of the Graft Bonds in PVDF–g–St Films by Boiling Xylene Extraction and the Determination of the Molecular Weight of the Graft Chains "],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:50:00.082885+00:00"}