{"created":"2023-05-15T14:55:41.614423+00:00","id":75620,"links":{},"metadata":{"_buckets":{"deposit":"992cc542-bb43-4d23-a157-6e9581a4024c"},"_deposit":{"created_by":1,"id":"75620","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"75620"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00075620","sets":["1"]},"author_link":["764194","764191","764193","764195","764190","764192"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-04","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"33","bibliographicPageStart":"27","bibliographicVolumeNumber":"520","bibliographic_titles":[{"bibliographic_title":"Journal of Nuclear Materials"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In the Fukushima Daiichi nuclear power station accident in March 2011, fuel debris was formed when fuel materials reacted with various structural materials in reactor core. Fuel debris retrieval is expected to start in 2021 for decommissioning of the damaged plants. To perform this activity safely, it is necessary to know the properties of the fuel debris. In this study, we investigated the reaction of UO2, stainless steel (SS) components, and ZrO2 at high temperature under oxidizing and reducing conditions, and determined the valence state of uranium in the products, such as CrUO4 and (Fex, Cr1−x)UO4, by X-ray absorption near edge structure (XANES) spectroscopy. Mixed powders of UO2 and SS, Fe, and/or Cr were heated in Ar + 2% O2 (oxidizing condition) or Ar + 10% H2 (reducing condition) at a flow rate of 20 mL/min for 2 h at 1473 or 1673 K. After heat treatment, the phase relation of the products was analyzed by powder X-ray diffraction and scanning electron microscopy with energy-dispersive X-ray spectroscopy. Under reducing conditions, UO2 did not react with SS, Fe, Cr, or ZrO2. In contrast, under oxidizing conditions, UO2 reacted with SS and Cr to form CrUO4 or (Fex, Cr1−x)UO4 at 1473 and 1673 K. When the UO2 and Fe mixture was heated under oxidizing conditions, the Fe2O3 phase coexisted with U3O8 at 1473 K, whereas FeUO4 formed at 1673 K. When the UO2, Fe, and Cr mixtures were heated at 1473 K under the oxidizing condition, the molar ratio of Fe/Cr in the (Fex, Cr1−x)UO4 phase corresponded to the initial molar ratio in the sample. As the iron content of these samples increased, all three lattice parameters of (Fex, Cr1−x)UO4 approached those of FeUO4. XANES spectra revealed that the oxidation state of uranium in CrUO4 and (Fex, Cr1−x)UO4 is pentavalent.","subitem_description_type":"Abstract"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jnucmat.2019.03.055","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.sciencedirect.com/science/article/pii/S0022311518312844","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022-3115","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Akiyama, Daisuke"}],"nameIdentifiers":[{"nameIdentifier":"764190","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Akiyama, Hidenori"}],"nameIdentifiers":[{"nameIdentifier":"764191","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uehara, Akihiro"}],"nameIdentifiers":[{"nameIdentifier":"764192","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kirishima, Akira"}],"nameIdentifiers":[{"nameIdentifier":"764193","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sato, Nobuaki"}],"nameIdentifiers":[{"nameIdentifier":"764194","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uehara, Akihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"764195","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Phase analysis of uranium oxides after reaction with stainless steel components and ZrO2 at high temperature by XRD, XAFS, and SEM/EDX","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Phase analysis of uranium oxides after reaction with stainless steel components and ZrO2 at high temperature by XRD, XAFS, and SEM/EDX"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-04-17"},"publish_date":"2019-04-17","publish_status":"0","recid":"75620","relation_version_is_last":true,"title":["Phase analysis of uranium oxides after reaction with stainless steel components and ZrO2 at high temperature by XRD, XAFS, and SEM/EDX"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T00:37:59.915029+00:00"}