{"created":"2023-05-15T14:53:53.978759+00:00","id":73392,"links":{},"metadata":{"_buckets":{"deposit":"ac3d71f7-d0c5-404d-b741-59108166cc3b"},"_deposit":{"created_by":1,"id":"73392","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"73392"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00073392","sets":["10:26"]},"author_link":["722884","722885"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2018-08-04","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"ビタミンCやビタミンE、フラボノイド類などの抗酸化物質は非常に効率良く活性酸素種やフリーラジカルを消去することが知られている。本講義では、活性酸素種のモデルとして安定有機ラジカルを用い、抗酸化物質のフリーラジカル消去活性を速度論的に評価する方法を紹介する。また、このフリーラジカル消去反応の律速段階が水素原子移動か電子移動かを見分ける方法について述べ、トンネル効果の有無を含む反応機構の解析法ついても紹介する。さらに、反応機構の知見に基づき、フリーラジカル消去活性の向上を目的として設計および合成した新規抗酸化物質についても紹介する。","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"フリーラジカルサマースクール2018 in 草津","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中西, 郁夫"}],"nameIdentifiers":[{"nameIdentifier":"722884","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西 郁夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"722885","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"抗酸化物質によるフリーラジカル消去反応の量子論的解析","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"抗酸化物質によるフリーラジカル消去反応の量子論的解析"}]},"item_type_id":"10005","owner":"1","path":["26"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-08-07"},"publish_date":"2018-08-07","publish_status":"0","recid":"73392","relation_version_is_last":true,"title":["抗酸化物質によるフリーラジカル消去反応の量子論的解析"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T19:29:48.491227+00:00"}