{"created":"2023-05-15T14:51:46.867239+00:00","id":70785,"links":{},"metadata":{"_buckets":{"deposit":"2ac44b86-2305-4506-b139-ef9b2ca8ef92"},"_deposit":{"created_by":1,"id":"70785","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"70785"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00070785","sets":["10:28"]},"author_link":["695425","695419","695420","695418","695426","695421","695427","695423","695424","695422"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2012-06-01","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"室温で安定な活性酸素種モデル(DPPHラジカル)を含むアセトニトリル溶液に、ルイス酸性の強い金属イオンであるスカンジウムイオン(Sc3+)を添加するとDPPHラジカルは不均化した。一方、Sc3+よりも弱いルイス酸であるマグネシウムイオン(Mg2+)を添加してもDPPHラジカルは変化しなかったが、反応系に酢酸を添加するとDPPHラジカルの不均化反応は進行した。Mg2+よりさらに弱いルイス酸であるリチウムでイオンと酢酸を添加するとDPPHラジカルの不均化反応はゆっくりと進行した。したがってDPPHラジカルの不均化反応はルイス酸の強さによって変化することがわかった。","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"第22回金属の関与する生体関連反応シンポジウム（SRM2012）","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"川島, 知憲"}],"nameIdentifiers":[{"nameIdentifier":"695418","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西, 郁夫"}],"nameIdentifiers":[{"nameIdentifier":"695419","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大久保, 敬"}],"nameIdentifiers":[{"nameIdentifier":"695420","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"福住, 俊一"}],"nameIdentifiers":[{"nameIdentifier":"695421","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小澤, 俊彦"}],"nameIdentifiers":[{"nameIdentifier":"695422","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松本, 謙一郎"}],"nameIdentifiers":[{"nameIdentifier":"695423","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"川島 知憲","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"695424","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西 郁夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"695425","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大久保 敬","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"695426","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松本 謙一郎","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"695427","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"ルイス酸性を有するレドックス不活性な金属イオンによるDPPHラジカルの不均化反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ルイス酸性を有するレドックス不活性な金属イオンによるDPPHラジカルの不均化反応"}]},"item_type_id":"10005","owner":"1","path":["28"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-06-05"},"publish_date":"2012-06-05","publish_status":"0","recid":"70785","relation_version_is_last":true,"title":["ルイス酸性を有するレドックス不活性な金属イオンによるDPPHラジカルの不均化反応"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T19:58:52.337105+00:00"}