{"created":"2023-05-15T14:51:27.201895+00:00","id":70335,"links":{},"metadata":{"_buckets":{"deposit":"af0bee69-69c2-44c6-add5-114a16e6842d"},"_deposit":{"created_by":1,"id":"70335","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"70335"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00070335","sets":["10:28"]},"author_link":["690699","690703","690705","690708","690700","690707","690698","690710","690701","690697","690704","690706","690709","690702"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2010-11-21","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The phenolate anion derived from a vitamin E model, 2,2,5,7,8-pentamethylchroman-6-ol (PMC), in the presence of a strong base is reported to reduce molecular oxygen to generate superoxide anion, one of reactive oxygen species, in acetonitrile (MeCN) (Org. Biomol. Chem. 1:4085; 2003).  However, very little is known about the detailed electron-transfer properties of phenolate anions derived from phenolic antioxidants.  In this study, we report the PMC anion can act as a strong electron donor to 2,2-diphenyl-1-picrylhydrazyl radical as well as to a series of p-benzoquinones in MeCN.  The kinetic data obtained in this study were evaluated in light of the Marcus theory of electron transfer, providing valuable insight into the electron-transfer properties of the phenolate anions derived from phenolic antioxidants.","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"SFRBM/SFRRI 2010","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakanishi, Ikuo"}],"nameIdentifiers":[{"nameIdentifier":"690697","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohkubo, Kei"}],"nameIdentifiers":[{"nameIdentifier":"690698","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kawashima, Tomonori"}],"nameIdentifiers":[{"nameIdentifier":"690699","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Inami, Keiko"}],"nameIdentifiers":[{"nameIdentifier":"690700","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsumoto, Kenichiro"}],"nameIdentifiers":[{"nameIdentifier":"690701","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuhara, Kiyoshi"}],"nameIdentifiers":[{"nameIdentifier":"690702","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okuda, Haruhiro"}],"nameIdentifiers":[{"nameIdentifier":"690703","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mochizuki, Masataka"}],"nameIdentifiers":[{"nameIdentifier":"690704","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuzumi, Shunichi"}],"nameIdentifiers":[{"nameIdentifier":"690705","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ozawa, Toshihiko"}],"nameIdentifiers":[{"nameIdentifier":"690706","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Anzai, Kazunori"}],"nameIdentifiers":[{"nameIdentifier":"690707","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西 郁夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"690708","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"川島 知憲","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"690709","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松本 謙一郎","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"690710","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"Electron-Transfer Properties of the Phenolate Anion Derived from a Vitamin E Model in the Presence of a Strong Base in an Aprotic Medium","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electron-Transfer Properties of the Phenolate Anion Derived from a Vitamin E Model in the Presence of a Strong Base in an Aprotic Medium"}]},"item_type_id":"10005","owner":"1","path":["28"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-11-24"},"publish_date":"2010-11-24","publish_status":"0","recid":"70335","relation_version_is_last":true,"title":["Electron-Transfer Properties of the Phenolate Anion Derived from a Vitamin E Model in the Presence of a Strong Base in an Aprotic Medium"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T20:04:07.546635+00:00"}