{"created":"2023-05-15T14:51:00.116248+00:00","id":69719,"links":{},"metadata":{"_buckets":{"deposit":"2c5326b3-88ae-4cc5-a052-c324dde10a04"},"_deposit":{"created_by":1,"id":"69719","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"69719"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00069719","sets":["10:28"]},"author_link":["684402","684400","684399","684401","684396","684391","684406","684407","684403","684393","684395","684398","684405","684392","684404","684394","684397"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2009-03-28","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"ミツバチの巣から得られるプロポリスは、産地によってその成分や活性が異なるが、ブラジル産プロポリスには、非常に優れた抗酸化活性を示すアルテピリンＣと呼ばれるフェノール化合物が含まれていることが知られている。本研究では、アルテピリンＣの抗酸化活性を増強する目的で、種々のアルテピリンＣ誘導体を合成し、ラジカル消去活性を速度論的に検討した。その結果、ラジカル消去活性がアルテピリンＣよりも約８倍高い誘導体を得た。また、密度汎関数計算の結果から、反応は電子移動を経由せず、フェノール性水酸基からの一段階水素原子移動機構で進行することが示唆された。","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"日本薬学会第129年会","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中西, 郁夫"}],"nameIdentifiers":[{"nameIdentifier":"684391","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"宇都, 義浩"}],"nameIdentifiers":[{"nameIdentifier":"684392","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大久保, 敬"}],"nameIdentifiers":[{"nameIdentifier":"684393","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"川島, 知憲"}],"nameIdentifiers":[{"nameIdentifier":"684394","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松本, 謙一郎"}],"nameIdentifiers":[{"nameIdentifier":"684395","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ｍａｎｄａ, Ｓｕｓｈｍａ"}],"nameIdentifiers":[{"nameIdentifier":"684396","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"堀, 均"}],"nameIdentifiers":[{"nameIdentifier":"684397","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"福原, 潔"}],"nameIdentifiers":[{"nameIdentifier":"684398","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"奥田, 晴宏"}],"nameIdentifiers":[{"nameIdentifier":"684399","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊古田, 暢夫"}],"nameIdentifiers":[{"nameIdentifier":"684400","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小澤, 俊彦"}],"nameIdentifiers":[{"nameIdentifier":"684401","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安西, 和紀"}],"nameIdentifiers":[{"nameIdentifier":"684402","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西 郁夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"684403","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松本 謙一郎","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"684404","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ｍａｎｄａ Ｓｕｓｈｍａ","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"684405","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小澤 俊彦","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"684406","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安西 和紀","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"684407","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"ブラジル産プロポリスに含まれるフェノール性抗酸化物質およびその誘導体のラジカル消去機構","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ブラジル産プロポリスに含まれるフェノール性抗酸化物質およびその誘導体のラジカル消去機構"}]},"item_type_id":"10005","owner":"1","path":["28"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-03-30"},"publish_date":"2009-03-30","publish_status":"0","recid":"69719","relation_version_is_last":true,"title":["ブラジル産プロポリスに含まれるフェノール性抗酸化物質およびその誘導体のラジカル消去機構"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T20:11:13.264267+00:00"}