@misc{oai:repo.qst.go.jp:00068714, author = {Fukuhara, Kiyoshi and Nakanishi, Ikuo and Kawashima, Tomonori and Tada, Ayako and Yakumaru, Haruko and Ohkubo, Kei and Kanazawa, Hideko and Urano, Shiro and Okuda, Haruhiro and Miyata, Naoki and Anzai, Kazunori and Ozawa, Toshihiko and Fukuzumi, Shunichi and Ikota, Nobuo and 中西 郁夫 and 川島 知憲 and 薬丸 晴子 and 安西 和紀 and 小澤 俊彦 and 伊古田 暢夫}, month = {Aug}, note = {The development of novel antioxidants showing a stronger radical-scavenging activity than natural antioxidants has attracted considerable interest to remove reactive oxygen species, which are known to induce oxidative stress and associated diseases. We herein report the synthesis, radical-scavenging activity, and redox behavior of planar catechin derivatives, in which catechol and chroman moieties in natural (+)-catechin are constrained to be planar. The spectroscopic and kinetic studies have demonstrated that the rate of the scavenging reaction of galvinoxyl radical by the planar catechin is about 5-fold faster than that by (+)-catechin in deaerated acetonitrile., International Society for Free Radical Research 13th Biennial Congress}, title = {Synthesis, Radical-Scavenging Activity, and Redox Behavior of Planar Catechin Derivatives}, year = {2006} }