{"created":"2023-05-15T14:48:08.657219+00:00","id":65980,"links":{},"metadata":{"_buckets":{"deposit":"653bb1cb-ef9a-42e1-b319-f67e52606f38"},"_deposit":{"created_by":1,"id":"65980","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"65980"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00065980","sets":["10:29"]},"author_link":["649822","649824","649823","649825"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2016-09-21","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では、単一の高分子基材膜の左右から各々異なるグラフト鎖を導入するという放射線非対称グラフト重合法を駆使し、新規バイポーラ膜の創製に着手した。エチレン・テトラフルオロエチレン共重合体(ETFE)膜にガンマ線を前照射した後、膜の片面側からスチレンスルホン酸ナトリウム(SSS)とアクリル酸(AA)の共グラフト重合、逆面側からクロロメチルスチレン(CMS)のグラフト重合を行った。このような非対称グラフト膜では、SSS/AAグラフト層とCMSグラフト層は明確に分離して形成されることがわかった。次いで、CMSユニットを4級化することで、カチオンおよびアニオン交換能を有するバイポーラ膜を作製できた。","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"第59回放射線化学討論会","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"澤田, 真一"}],"nameIdentifiers":[{"nameIdentifier":"649822","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"前川, 康成"}],"nameIdentifiers":[{"nameIdentifier":"649823","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"澤田 真一","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"649824","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"前川 康成","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"649825","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"新しい放射線グラフト重合法による非対称構造膜の創製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"新しい放射線グラフト重合法による非対称構造膜の創製"}]},"item_type_id":"10005","owner":"1","path":["29"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-09-30"},"publish_date":"2016-09-30","publish_status":"0","recid":"65980","relation_version_is_last":true,"title":["新しい放射線グラフト重合法による非対称構造膜の創製"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T20:54:06.321376+00:00"}