{"created":"2023-05-15T14:45:22.939292+00:00","id":62014,"links":{},"metadata":{"_buckets":{"deposit":"8b6a54e2-ba58-4290-a2e2-a70096a5176f"},"_deposit":{"created_by":1,"id":"62014","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"62014"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00062014","sets":["10:29"]},"author_link":["613437","613440","613445","613442","613439","613427","613428","613434","613438","613446","613447","613430","613436","613429","613443","613431","613441","613435","613433","613432","613444"],"item_10005_date_7":{"attribute_name":"発表年月日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2007-01-27","subitem_date_issued_type":"Issued"}]},"item_10005_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"我々は以前に、嫌気性条件下、メタノール(MeOH)中、ビタミンＥ類縁体、2,2,5,7,8-pentamethylchroman-6-ol (PMC)によるガルビノキシルラジカルやDPPHラジカルの消去活性が、ピリジンなどの塩基の存在下で、顕著に上昇することを明らかにした。本研究では、ビタミンＥのラジカル消去活性を増強する目的で、分子内に塩基性部位を有する３つの新規ビタミンＥ誘導体を合成し、ラジカル消去活性を速度論的に評価した。その結果、PMCよりも1.5〜3倍強力なラジカル消去活性を有する新規ビタミンＥ誘導体の開発に成功した。","subitem_description_type":"Abstract"}]},"item_10005_description_6":{"attribute_name":"会議概要（会議名, 開催地, 会期, 主催者等）","attribute_value_mlt":[{"subitem_description":"第18回ビタミンＥ研究会","subitem_description_type":"Other"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"川島, 知憲"}],"nameIdentifiers":[{"nameIdentifier":"613427","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西, 郁夫"}],"nameIdentifiers":[{"nameIdentifier":"613428","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"薬丸, 晴子"}],"nameIdentifiers":[{"nameIdentifier":"613429","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"乳井, 美奈子"}],"nameIdentifiers":[{"nameIdentifier":"613430","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ｍａｎｄａ, Ｓｕｓｈｍａ"}],"nameIdentifiers":[{"nameIdentifier":"613431","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大久保, 敬"}],"nameIdentifiers":[{"nameIdentifier":"613432","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"金澤, 秀子"}],"nameIdentifiers":[{"nameIdentifier":"613433","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"福原, 潔"}],"nameIdentifiers":[{"nameIdentifier":"613434","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"奥田, 晴宏"}],"nameIdentifiers":[{"nameIdentifier":"613435","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"福住, 俊一"}],"nameIdentifiers":[{"nameIdentifier":"613436","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小澤, 俊彦"}],"nameIdentifiers":[{"nameIdentifier":"613437","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊古田, 暢夫"}],"nameIdentifiers":[{"nameIdentifier":"613438","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安西, 和紀"}],"nameIdentifiers":[{"nameIdentifier":"613439","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"川島 知憲","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613440","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西 郁夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613441","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"薬丸 晴子","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613442","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"乳井 美奈子","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613443","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ｍａｎｄａ Ｓｕｓｈｍａ","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613444","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小澤 俊彦","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613445","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊古田 暢夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613446","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安西 和紀","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"613447","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"conference object","resourceuri":"http://purl.org/coar/resource_type/c_c94f"}]},"item_title":"分子内に塩基性部位を有する新規ビタミンＥ誘導体の合成とラジカル消去活性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"分子内に塩基性部位を有する新規ビタミンＥ誘導体の合成とラジカル消去活性"}]},"item_type_id":"10005","owner":"1","path":["29"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-01-30"},"publish_date":"2007-01-30","publish_status":"0","recid":"62014","relation_version_is_last":true,"title":["分子内に塩基性部位を有する新規ビタミンＥ誘導体の合成とラジカル消去活性"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T21:35:41.803999+00:00"}