{"created":"2023-05-15T14:38:05.171194+00:00","id":49137,"links":{},"metadata":{"_buckets":{"deposit":"76c36f7e-caee-494e-a4d3-74152ea7b582"},"_deposit":{"created_by":1,"id":"49137","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"49137"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00049137","sets":["1"]},"author_link":["495742","495739","495738","495736","495735","495741","495737","495743","495740"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-08","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"193-11","bibliographicPageStart":"193-1","bibliographicVolumeNumber":"25","bibliographic_titles":[{"bibliographic_title":"Journal of Polymer Research"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Grafted polymer substrates bearing diglycol amic acid (DA) ligands for Eu and Sm adsorption were prepared using a two-step post-grafting modification of polyethylene/polypropylene-g-poly(glycidyl methacrylate) (PE/PP-g-PGMA) that was synthesized through reversible addition-fragmentation chain transfer (RAFT)-mediated γ-radiation induced graft polymerization in emulsion phase. The PE/PP-g-PGMA prepared with RAFT mediation exhibited better reactivity towards amination reaction at 40 °C than the graft copolymers prepared without RAFT mediation, with the epoxide to amino group conversion of the former exceeding the latter by as much as 20%. The DA ligands were incorporated to the aminated graft copolymer by subsequent reaction with diglycolic anhydride to yield theDA-modified PE/PP-g-PGMAadsorbent. The effects of pH and competing ions on the uptake of Eu and Sm have been investigated. The DA-modified PE/PP-g-PGMA prepared with RAFT mediation showed higher Eu and\nSm adsorption percentage than the DA adsorbent that was synthesized without RAFT mediation. The DA-modified PE/PP-g-PGMA exhibited higher affinity for Eu over Cu and Fe in acidic solutions.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1007/s10965-018-1585-4 ","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://link.springer.com/article/10.1007/s10965-018-1585-4"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://link.springer.com/article/10.1007/s10965-018-1585-4","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1022-9760","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"フェルナンデス, マドリッド ジョーダン"}],"nameIdentifiers":[{"nameIdentifier":"495735","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ジョー"}],"nameIdentifiers":[{"nameIdentifier":"495736","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"植木, 悠二"}],"nameIdentifiers":[{"nameIdentifier":"495737","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lucille, V. Abad（Philippine Nuclear Research Institute）"}],"nameIdentifiers":[{"nameIdentifier":"495738","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山延, 健 （群馬大学）"}],"nameIdentifiers":[{"nameIdentifier":"495739","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"瀬古, 典明"}],"nameIdentifiers":[{"nameIdentifier":"495740","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"フェルナンデス マドリッド ジョーダン","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"495741","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"植木 悠二","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"495742","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"瀬古 典明","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"495743","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-08-13"},"publish_date":"2018-08-13","publish_status":"0","recid":"49137","relation_version_is_last":true,"title":["Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:21:00.363391+00:00"}