{"created":"2023-05-15T14:37:55.142148+00:00","id":48919,"links":{},"metadata":{"_buckets":{"deposit":"c1859464-e4a8-44f5-a269-3a677ddbe163"},"_deposit":{"created_by":1,"id":"48919","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"48919"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00048919","sets":["1"]},"author_link":["492827","492838","492835","492831","492836","492830","492828","492832","492834","492833","492839","492829","492837"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"30","bibliographicPageStart":"23","bibliographicVolumeNumber":"133","bibliographic_titles":[{"bibliographic_title":"Carbon"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We report the scanning tunneling microscope (STM) observation of the Li+ ion endohedral C60 on Cu(111), prepared by means of evaporation of a high-purity Li+@C60[PF6−] salt. The electronic state of Li+@C60 in the Li+@C60[PF6−] salt was also determined using photoemission and X-ray absorption spectroscopy, along with the density functional theory (DFT) calculations. In the salt, Li and PF6 had nearly single positive and negative charge, respectively; thus the C60 cage was practically neutral. The salt decomposed under ultra-high vacuum while heating at 400 °C. This allowed the selective deposition of Li+@C60 on Cu(111). Although secondary-ion mass spectroscopy of the deposited Li+@C60 film showed a decrease in the Li-content during evaporation, Li+@C60 was successfully identified using STM. The DFT calculations of Li+@C60 on Cu(111) suggested that the Li+ ion was singly charged and the location of the Li+ ion was displaced in an upward direction, which altered the local density of states in an upper section of C60, especially for LUMO+2. The calculated results were mostly in agreement with the bias-dependent STM and dI/dV images. However, an inconsistency was observed between the calculation and experiments in case of empty state imaging where tip-induced displacement of the Li+ ion may occur.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.carbon.2018.02.106","subitem_relation_type_select":"DOI"}}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamada, Y."}],"nameIdentifiers":[{"nameIdentifier":"492827","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"V., Kuklin A."}],"nameIdentifiers":[{"nameIdentifier":"492828","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sato, S."}],"nameIdentifiers":[{"nameIdentifier":"492829","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Esaka, F."}],"nameIdentifiers":[{"nameIdentifier":"492830","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sumi, N."}],"nameIdentifiers":[{"nameIdentifier":"492831","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Zhang, C."}],"nameIdentifiers":[{"nameIdentifier":"492832","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sasaki, M."}],"nameIdentifiers":[{"nameIdentifier":"492833","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kwon, E."}],"nameIdentifiers":[{"nameIdentifier":"492834","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kasama, Y."}],"nameIdentifiers":[{"nameIdentifier":"492835","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"V., Avramov P."}],"nameIdentifiers":[{"nameIdentifier":"492836","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakai, S."}],"nameIdentifiers":[{"nameIdentifier":"492837","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"アヴラモフ パベル","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"492838","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"境 誠司","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"492839","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electronic structure of Li+@C60: Photoelectron spectroscopy of the Li+@C60[PF6-] salt and STM of the single Li+@C60 molecules on Cu(111)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electronic structure of Li+@C60: Photoelectron spectroscopy of the Li+@C60[PF6-] salt and STM of the single Li+@C60 molecules on Cu(111)"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-05-08"},"publish_date":"2018-05-08","publish_status":"0","recid":"48919","relation_version_is_last":true,"title":["Electronic structure of Li+@C60: Photoelectron spectroscopy of the Li+@C60[PF6-] salt and STM of the single Li+@C60 molecules on Cu(111)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:22:52.724653+00:00"}