{"created":"2023-05-15T14:37:29.104786+00:00","id":48348,"links":{},"metadata":{"_buckets":{"deposit":"a8b3c38f-699b-4503-b818-658404164ebb"},"_deposit":{"created_by":1,"id":"48348","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"48348"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00048348","sets":["1"]},"author_link":["485914","485912","485909","485910","485913","485916","485911","485908","485915"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"36","bibliographicPageEnd":"45270-11","bibliographicPageStart":"45270-1","bibliographicVolumeNumber":"134","bibliographic_titles":[{"bibliographic_title":"Journal of Applied Polymer Science"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The successful reversible addition-fragmentation (RAFT)-mediated graft polymerization of glycidyl methacrylate (GMA) in emulsion phase from polyethylene/polypropylene nonwoven fabric using 4-cyano-4-[(phenylcarbonothioyl)thio]pentanoic acid under γ-irradiation at ambient condition is reported. While conventional graft polymerization in emulsion phase yielded grafted materials with low Dg values [<7.5% at 10% (wt/wt) GMA], addition of RAFT agent to the graft polymerization system allowed the synthesis of polyethylene/polypropylene-g-poly(glycidyl methacrylate) (PE/PP-g-PGMA) with more tunable degree of grafting (8% <  Dg <  94%) by controlling the grafting parameters. Relatively good control (PDI ~ 1.2 for selected grafting conditions) during polymerization was attained at 100:1 monomer-to-RAFT agent molar ratio. The number average molecular weight of free PGMA increased as a function of monomer conversion. NMR analyses of the free PGMA homopolymers indicate the presence of dithiobenzoate group from 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid on the polymer chain. The reactive pendant oxirane group of the grafted GMA can be modified for various environmental and industrial applications.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/APP.45270","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://onlinelibrary.wiley.com/doi/10.1002/app.45270/full"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://onlinelibrary.wiley.com/doi/10.1002/app.45270/full","subitem_relation_type_select":"URI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1097-4628","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"フェルナンデス, マドリッド ジョーダン"}],"nameIdentifiers":[{"nameIdentifier":"485908","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ジョーダン"}],"nameIdentifiers":[{"nameIdentifier":"485909","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"植木, 悠二"}],"nameIdentifiers":[{"nameIdentifier":"485910","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lucille, V. Abad（Philippine Nuclear Research Institute）"}],"nameIdentifiers":[{"nameIdentifier":"485911","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山延, 健 （群馬大学）"}],"nameIdentifiers":[{"nameIdentifier":"485912","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"瀬古, 典明"}],"nameIdentifiers":[{"nameIdentifier":"485913","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"フェルナンデス マドリッド ジョーダン","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"485914","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"植木 悠二","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"485915","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"瀬古 典明","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"485916","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"RAFT-mediated graft polymerization of glycidyl methacrylate in emulsion from polyethylene/polypropylene initiated with γ-radiation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"RAFT-mediated graft polymerization of glycidyl methacrylate in emulsion from polyethylene/polypropylene initiated with γ-radiation"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-05"},"publish_date":"2017-10-05","publish_status":"0","recid":"48348","relation_version_is_last":true,"title":["RAFT-mediated graft polymerization of glycidyl methacrylate in emulsion from polyethylene/polypropylene initiated with γ-radiation"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:29:08.874401+00:00"}