@article{oai:repo.qst.go.jp:00048348,
 author = {フェルナンデス, マドリッド ジョーダン and ジョーダン and 植木, 悠二 and Lucille, V. Abad（Philippine Nuclear Research Institute） and 山延, 健 （群馬大学） and 瀬古, 典明 and フェルナンデス マドリッド ジョーダン and 植木 悠二 and 瀬古 典明},
 issue = {36},
 journal = {Journal of Applied Polymer Science},
 month = {Sep},
 note = {The successful reversible addition-fragmentation (RAFT)-mediated graft polymerization of glycidyl methacrylate (GMA) in emulsion phase from polyethylene/polypropylene nonwoven fabric using 4-cyano-4-[(phenylcarbonothioyl)thio]pentanoic acid under γ-irradiation at ambient condition is reported. While conventional graft polymerization in emulsion phase yielded grafted materials with low Dg values [<7.5% at 10% (wt/wt) GMA], addition of RAFT agent to the graft polymerization system allowed the synthesis of polyethylene/polypropylene-g-poly(glycidyl methacrylate) (PE/PP-g-PGMA) with more tunable degree of grafting (8% <  Dg <  94%) by controlling the grafting parameters. Relatively good control (PDI ~ 1.2 for selected grafting conditions) during polymerization was attained at 100:1 monomer-to-RAFT agent molar ratio. The number average molecular weight of free PGMA increased as a function of monomer conversion. NMR analyses of the free PGMA homopolymers indicate the presence of dithiobenzoate group from 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid on the polymer chain. The reactive pendant oxirane group of the grafted GMA can be modified for various environmental and industrial applications.},
 pages = {45270-1--45270-11},
 title = {RAFT-mediated graft polymerization of glycidyl methacrylate in emulsion from polyethylene/polypropylene initiated with γ-radiation},
 volume = {134},
 year = {2017}
}