@article{oai:repo.qst.go.jp:00047978, author = {Nakamura, Shin and Mitsui, Takaya and Fujiwara, Kosuke and Ikeda, Naoshi and Kobayashi, Yasuhiro and Shimomura, Susumu and 三井 隆也}, journal = {Hyperfine Interactions}, month = {Nov}, note = {A Mössbauer diffractometer has been developed by using 57Fe nuclear resonant scattering apparatus at SPring-8 BL11XU in order to obtain a crystal-site-selective Mössbauer spectrum. A _x120579_-2_x120579_ goniometer was newly installed between the nuclear monochromator and a detector. From a single crystal Fe3O4 mounted on the goniometer, the 111, 222, and 220 reflected γ-rays were used to collect the diffraction spectra at room temperature. The intensity ratio of the two subspectra, corresponding to A- and B-site Fe ions, changes notably according to the reflection index. The diffraction spectrum is composed of a major absorption spectrum and a minor emission spectrum. The former is given by the γ-ray due to the electron scattering and nuclear absorption, whereas the latter is given by the γ-ray due to the nuclear resonant scattering. Interference effects between these two γ-rays are also seen as line broadenings, asymmetric line shapes, and slope of the base lines. These features can be successfully expressed by a Fano function. We consider that the emission spectrum due to the nuclear resonant scattering represents crystal-site-selective Mössbauer spectrum.}, pages = {157-1--157-9}, title = {Development of Mössbauer diffractometer by using nuclear resonant scattering at SPring-8 BL11XU}, volume = {237}, year = {2016} }