{"created":"2023-05-15T14:37:11.968324+00:00","id":47955,"links":{},"metadata":{"_buckets":{"deposit":"68fac745-5733-410d-9465-b1ce1bccee30"},"_deposit":{"created_by":1,"id":"47955","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"47955"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00047955","sets":["1"]},"author_link":["481442","481448","481440","481450","481453","481439","481454","481452","481455","481451","481441","481447","481446","481443","481449","481444","481445"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"17","bibliographicPageEnd":"6067","bibliographicPageStart":"6062","bibliographicVolumeNumber":"28","bibliographic_titles":[{"bibliographic_title":"Chemistry of Materials"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The valence distribution and local structure of Bi1−xPbxNiO3 (x ≤ 0.25) were investigated by comprehensive studies of Rietveld analysis of synchrotron X-ray diffraction (SXRD) data, X-ray absorption spectroscopy (XAS), hard X-ray photoemission spectroscopy (HAXPES), and atomic pair distribution function (PDF) analysis of synchrotron X-ray total scattering data. Disproportionation of Bi ions into Bi3+ and Bi5+ accompanied by an intermetallic charge transfer between Bi5+ and Ni2+ was observed for all the samples, but it was a longranged one with distinct crystallographic sites in the P1̅ triclinic structure for x ≤ 0.15, while the ordering was short-ranged for x = 0.20 and 0.25. In the case of the higher Pb concentration, the long-range order does not grow due to the obstruction of the substituent Pb and a macroscopically glassy charge distribution appears.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.chemmater.6b01160","subitem_relation_type_select":"DOI"}}]},"item_8_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.6b01160"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.6b01160","subitem_relation_type_select":"URI"}}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakano, Kiho"}],"nameIdentifiers":[{"nameIdentifier":"481439","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Oka, Kengo"}],"nameIdentifiers":[{"nameIdentifier":"481440","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"綿貫, 徹"}],"nameIdentifiers":[{"nameIdentifier":"481441","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mizumaki, Masaichiro"}],"nameIdentifiers":[{"nameIdentifier":"481442","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"町田, 晃彦"}],"nameIdentifiers":[{"nameIdentifier":"481443","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安居院, あかね"}],"nameIdentifiers":[{"nameIdentifier":"481444","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kim, Hyunjeong"}],"nameIdentifiers":[{"nameIdentifier":"481445","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Komiyama, Jun"}],"nameIdentifiers":[{"nameIdentifier":"481446","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mizokawa, Takashi"}],"nameIdentifiers":[{"nameIdentifier":"481447","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishikubo, Takumi"}],"nameIdentifiers":[{"nameIdentifier":"481448","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hattori, Yuichiro"}],"nameIdentifiers":[{"nameIdentifier":"481449","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ueda, Shigenori"}],"nameIdentifiers":[{"nameIdentifier":"481450","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakai, Yuki"}],"nameIdentifiers":[{"nameIdentifier":"481451","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Azuma, Masaki"}],"nameIdentifiers":[{"nameIdentifier":"481452","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"綿貫 徹","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"481453","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"町田 晃彦","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"481454","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安居院 あかね","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"481455","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Glassy distribution of Bi3+Bi5+ in Bi1-xPbx NiO3 and negative thermal expansion induced by　intermetallic charge transfer","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Glassy distribution of Bi3+Bi5+ in Bi1-xPbx NiO3 and negative thermal expansion induced by　intermetallic charge transfer"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-05-22"},"publish_date":"2017-05-22","publish_status":"0","recid":"47955","relation_version_is_last":true,"title":["Glassy distribution of Bi3+Bi5+ in Bi1-xPbx NiO3 and negative thermal expansion induced by　intermetallic charge transfer"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:33:38.871951+00:00"}