{"created":"2023-05-15T14:37:11.445662+00:00","id":47943,"links":{},"metadata":{"_buckets":{"deposit":"43bcde71-8a20-4481-8a57-fae2909e1d6e"},"_deposit":{"created_by":1,"id":"47943","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"47943"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00047943","sets":["1"]},"author_link":["481308","481306","481309","481307","481305","481304"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1016","bibliographicPageStart":"1007","bibliographicVolumeNumber":"295","bibliographic_titles":[{"bibliographic_title":"Colloid and Polymer Science"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The graft polymerization of glycidyl methacrylate\nfrom irradiated polyethylene/polypropylene (PE/PP) in the\npresence of the chain transfer agent 4-cyano-\n4-((phenylcarbonothioyl)thio) pentanoic acid (CPPA) was\nstudied at 40 °C using pre-irradiation grafting technique.\nFree radical active sites on polyethylene/polypropylene were\nformed by electron beam irradiation in nitrogen atmosphere\nand dry ice temperature. Compared to the conventional\ngrafting method, addition of the chain transfer agent resulted\nin lower amount of grafted poly(glycidyl methacrylate)\n(PGMA) on the PE/PP trunk polymer. The calculated degree\nof grafting increased with increment in absorbed dose and\nreaction time but decreased with increasing glycidyl methacrylate\nconcentration, at fixed monomer to CPPA ratio, and\namount of CPPA. An apparent first-order dependence of conversion\non monomer concentration was observed. The free\npoly(glycidyl methacrylate) that was formed in the polymerization\nmixture during grafting in the presence of CPPA had\nMn which increased with reaction time and polydispersity index\n(PDI) values less than 2. NMR analysis of the PGMA\nhomopolymer indicates the presence of dithiobenzoate group\nfrom CPPA at one end of the polymer chain. The pristine and\ngrafted trunk polymers were characterized with FTIR, TGA,\nand SEM-EDX.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1007/s00396-017-4088-7","subitem_relation_type_select":"DOI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1435-1536","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ジョーダン, フェルナ ンデス マドリッド"}],"nameIdentifiers":[{"nameIdentifier":"481304","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lucille, V. Abad（Philippine Nuclear Research Institute）"}],"nameIdentifiers":[{"nameIdentifier":"481305","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山延, 健 （群馬大学）"}],"nameIdentifiers":[{"nameIdentifier":"481306","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"瀬古, 典明"}],"nameIdentifiers":[{"nameIdentifier":"481307","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"フェルナンデス マドリッド ジョーダン","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"481308","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"瀬古 典明","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"481309","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-05-15"},"publish_date":"2017-05-15","publish_status":"0","recid":"47943","relation_version_is_last":true,"title":["Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:33:47.405713+00:00"}