@article{oai:repo.qst.go.jp:00047918, author = {Wasin, (Kyoto Univ) Tuchinda and Enomoto, (Osaka Univ.) Kazuyuki and Sakurai, (Kyoto Univ) Tsuneaki and S., Padalkar (Kyoto Univ) Vikas and Lok, Cheng (Osaka Univ.) Hoi and T., Tang (Osaka Univ.) Michael and Horio, (Kyoto Univ) Akifumi and Sakamaki, (Kyoto Univ) Daisuke and Omichi, (Osaka Univ.) Masaaki and Saeki, (Osaka Univ.) Akinori and Kikuchi, (Osaka Univ.) Kazuya and Hori, (Osaka Univ.) Yuichiro and Chiba, Atsuya and Kamiya, Tomihiro and Saito, Yuuichi and Sugimoto, Masaki and Seki, (Kyoto Univ) Shu and 千葉 敦也 and 神谷 富裕 and 齋藤 勇一 and 杉本 雅樹}, issue = {6}, journal = {ACS SENSORS}, month = {Jun}, note = {“Clickable” nanowires with well-defined and uniform structures made of conjugated polyfluorene polymers were successfully fabricated by single particle nanofabrication technique (SPNT). Poly[(9,9-dihex-5-yn-1-ylfluorenyl-2,7-diyl)-co-(9,9′-di-noctylfluorenyl- 2,7-diyl)] (F6E8) and poly[(9,9-dihex-5-yn-1-ylfluorenyl- 2,7-diyl)-co-(2,2′-bithiophene)] (F6E2T) underwent an efficient cross-linking reaction upon irradiation, resulting in formation of one-dimensional nanostructures with high and desired aspect ratio reaching up to 200. Alkyne groups on the surface of nanowires were functionalized effectively by click reaction with fluorescent 5- TAMRA-PEG3-azide, which was confirmed by confocal microscopy. Substrates functionalized with the nanowires provide dramatic expansion of “clickable” surface area immobilized directly with TAMRA, and the fluorescence resonance energy transfer (FRET) processes between TAMRA and nanowire backbones are demonstrated as biological sensing platforms.}, pages = {766--774}, title = {Fabrication of “Clickable” Polyfluorene Nanowires with High Aspect Ratio as Biological Sensing Platforms}, volume = {1}, year = {2016} }