{"created":"2023-05-15T14:37:01.062999+00:00","id":47706,"links":{},"metadata":{"_buckets":{"deposit":"26f7c75d-6b43-41e3-9541-d213e35a54a0"},"_deposit":{"created_by":1,"id":"47706","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"47706"},"status":"published"},"_oai":{"id":"oai:repo.qst.go.jp:00047706","sets":["1"]},"author_link":["478714","478713","478704","478708","478709","478716","478715","478707","478710","478711","478712","478705","478706"],"item_8_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"3370","bibliographicPageStart":"3367","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"ChemistrySelect"}]}]},"item_8_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A stable radical, 2,2-diphenyl-1-picrylhydrazyl (DPPH), frequently used as a reactivity model of reactive oxygen species, was successfully solubilized in water by forming an inclusion complex with beta-cyclodextrin (b-CD), but the yield was less than 1%.  When b-CD was replaced with 2,6-di-O-methyl-beta-cyclodextrin (DM-b-CD), the solubility of DPPH in water improved significantly.  However, the reactivity of DM-b-CD-solubilized DPPH toward water-soluble antioxidants, such as ascorbate, Trolox, and caffeic acid, was significantly lower than that of b-CD-solubilized DPPH due to the steric hindrance of the methyl groups in DM-b-CD.  Therefore, b-CD-solubilized DPPH is suitable for evaluating the innate activity of water-soluble antioxidants.","subitem_description_type":"Abstract"}]},"item_8_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH"}]},"item_8_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/slct.201600745","subitem_relation_type_select":"DOI"}}]},"item_8_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2365-6549","subitem_source_identifier_type":"ISSN"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakanishi, Ikuo"}],"nameIdentifiers":[{"nameIdentifier":"478704","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohkubo, Kei"}],"nameIdentifiers":[{"nameIdentifier":"478705","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamibayashi, Masato"}],"nameIdentifiers":[{"nameIdentifier":"478706","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ogawa, Yukihiro"}],"nameIdentifiers":[{"nameIdentifier":"478707","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ozawa, Toshihiko"}],"nameIdentifiers":[{"nameIdentifier":"478708","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsumoto, Kenichiro"}],"nameIdentifiers":[{"nameIdentifier":"478709","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuzumi, Shunichi"}],"nameIdentifiers":[{"nameIdentifier":"478710","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中西 郁夫","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"478711","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"大久保 敬","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"478712","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"上林 將人","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"478713","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小川 幸大","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"478714","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小澤 俊彦","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"478715","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"松本 謙一郎","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"478716","nameIdentifierScheme":"WEKO"}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reactivity of 2,2-Diphenyl-1-picrylhydrazyl Solubilized in Water by β-Cyclodextrin and Its Methylated Derivative","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reactivity of 2,2-Diphenyl-1-picrylhydrazyl Solubilized in Water by β-Cyclodextrin and Its Methylated Derivative"}]},"item_type_id":"8","owner":"1","path":["1"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-04-19"},"publish_date":"2017-04-19","publish_status":"0","recid":"47706","relation_version_is_last":true,"title":["Reactivity of 2,2-Diphenyl-1-picrylhydrazyl Solubilized in Water by β-Cyclodextrin and Its Methylated Derivative"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-15T23:36:27.264499+00:00"}